New η5- and μ-(O)-Rh(I) phenoxide complexes:: synthesis, characterisation and unconventional reactivity of η5-complexes towards carbon dioxide

被引：8

作者：

Aresta, M

Dibenedetto, A

Pascale, M

Quaranta, E

Tommasi, I

机构：

[1] Univ Bari, Dipartmento Chim, I-70126 Bari, Italy

[2] CNR, Ctr MISO, I-70126 Bari, Italy

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2000年 / 605卷 / 02期

关键词：

phenoxides; phenoxo-complexes; rhodium complexes; carbon dioxide; carboxylation;

D O I：

10.1016/S0022-328X(00)00217-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis, analytical and spectroscopic characterisation, and reactivity of three new Rh(I)-phenoxide complexes of formula Rh-2(mu-OPh)(2)(C2H4)(4) (1), Rh(C2H4)(2)(eta(5)-OPh) (2) and Rh(diphos)(eta(5)-OPh) (4) [diphos = 1,2-bis(diphenylphosphino)ethane] are reported. Both the eta(5)- and mu-(O) modes of bonding have been found. The eta(5)-complexes are quite air-sensitive. The reactivity towards carbon dioxide is described and the formation of an emicarbonate is reported with the O-bonded phenoxide. A ring carboxylation occurs with eta(5)-complexes. (C) 2000 Published by Elsevier Science S.A. All rights reserved.

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收藏

页码：143 / 150

页数：8

相关论文

共 58 条

[1] INTERACTION OF CARBON-DIOXIDE WITH COORDINATIVELY UNSATURATED RHODIUM(I) COMPLEXES WITH THE LIGAND 1,2-BIS(DIPHENYLPHOSPHINO)ETHANE [J].

ALBANO, P ;

ARESTA, M ;

MANASSERO, M .

INORGANIC CHEMISTRY, 1980, 19 (04) :1069-1072

[2] SOME CATALYTIC PROPERTIES OF RH(DIPHOS) (ETA-BPH4) [J].

ALBANO, P ;

ARESTA, M .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1980, 190 (03) :243-246

[3] FORMATION OF ACRYLIC-ACID DERIVATIVES FROM THE REACTION OF CO2 WITH ETHYLENE COMPLEXES OF MOLYBDENUM AND TUNGSTEN [J].

ALVAREZ, R ;

CARMONA, E ;

COLEHAMILTON, DJ ;

GALINDO, A ;

GUTIERREZPUEBLA, E ;

MONGE, A ;

POVEDA, ML ;

RUIZ, C .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (19) :5529-5531

[4] STABILIZATION OF THE DIENONYLIC FORM OF THE A-RING OF BETA-ESTRADIOL BY THE CP-STAR-RH FRAGMENT - X-RAY STRUCTURE OF ALPHA-[(ETA-5-ESTRADIENONYL)RHCP-STAR]BF4 (CP-STAR = C5ME5) [J].

AMOURI, H ;

GRUSELLE, M ;

JACKSON, PA ;

JAOUEN, G ;

VAISSERMANN, J .

ORGANOMETALLICS, 1990, 9 (11) :2871-2873

[5] TERTIARY PHOSPHINE COMPLEXES OF NICKEL(O) AND NICKEL(I) - NEW DINITROGEN COMPLEXES OF NICKEL(O) [J].

ARESTA, M ;

NOBILE, CF ;

SACCO, A .

INORGANICA CHIMICA ACTA, 1975, 12 (02) :167-178

[6]

Aresta M, 1995, GAZZ CHIM ITAL, V125, P509

[7]

Aresta M, 1997, CHEMTECH, V27, P32

[8] SYNTHESIS, CHARACTERIZATION AND REACTIVITY OF [RH(BPY)(C2H4)CL] - A STUDY ON THE REACTION WITH C-1 MOLECULES (CH2O, CO2) AND NABPH(4) [J].

ARESTA, M ;

QUARANTA, E .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 463 (1-2) :215-221

[9] TETRAPHENYLBORATE COORDINATION CHEMISTRY - SYNTHESIS, SOLID-STATE AND SOLUTION CHARACTERIZATION, AND PROPERTIES OF ([(C2H4)2RH(ETA(6)-PH)]2BPH2)O3SCF3 AND ([(C2H4)2RH(ETA(6)-PH)]3BPH)(O3SCF3)2 - THE 1ST EXAMPLES OF A TETRAPHENYLBORATE ANION ACTING AS A 12-E OR 18-E DONOR TO METAL CENTERS [J].

ARESTA, M ;

QUARANTA, E ;

ALBINATI, A .

ORGANOMETALLICS, 1993, 12 (06) :2032-2043

[10]

ARESTA M, 1993, GAZZ CHIM ITAL, V123, P271

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