Observation of quantum coherence in mesoscopic molecular magnets

被引:67
作者
Luis, F
Mettes, FL
Tejada, J
Gatteschi, D
de Jongh, LJ
机构
[1] Leiden Univ, Kamerlingh Onnes Lab, NL-2300 RA Leiden, Netherlands
[2] Univ Barcelona, Dept Fis Fonamental, E-08028 Barcelona, Spain
[3] Univ Florence, Dept Chem, I-50144 Florence, Italy
关键词
D O I
10.1103/PhysRevLett.85.4377
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
By applying a transverse magnetic field B-perpendicular to of sufficient strength to the uniaxial molecular magnets Fe-8 and Mn-12, the tunneling splitting Delta (t) of their S = +/-10 magnetic ground states can be made large compared to perturbations such as hyperfine and dipolar interactions. We present evidence for such a Delta (t) from magnetic specific heat data below 1 K that is consistent with coherent quantum mechanical tunneling in a "mesoscopic" system under such conditions.
引用
收藏
页码:4377 / 4380
页数:4
相关论文
共 23 条
  • [1] Superparamagnetic-like behavior in an octanuclear iron cluster
    Barra, AL
    Debrunner, P
    Gatteschi, D
    Schulz, CE
    Sessoli, R
    [J]. EUROPHYSICS LETTERS, 1996, 35 (02): : 133 - 138
  • [2] High-frequency EPR spectra of a molecular nanomagnet: Understanding quantum tunneling of the magnetization
    Barra, AL
    Gatteschi, D
    Sessoli, R
    [J]. PHYSICAL REVIEW B, 1997, 56 (13): : 8192 - 8198
  • [3] Phonon-assisted tunneling in high-spin molecules: Experimental evidence
    Bellessa, G
    Vernier, N
    Barbara, B
    Gatteschi, D
    [J]. PHYSICAL REVIEW LETTERS, 1999, 83 (02) : 416 - 419
  • [4] Neutron spectroscopy for the magnetic anisotropy of molecular clusters
    Caciuffo, R
    Amoretti, G
    Murani, A
    Sessoli, R
    Caneschi, A
    Gatteschi, D
    [J]. PHYSICAL REVIEW LETTERS, 1998, 81 (21) : 4744 - 4747
  • [5] del Barco E, 1999, EUROPHYS LETT, V47, P722, DOI 10.1209/epl/i1999-00450-8
  • [6] MAGNETIC-PROPERTIES OF AN OCTANUCLEAR IRON(III) CATION
    DELFS, C
    GATTESCHI, D
    PARDI, L
    SESSOLI, R
    WIEGHARDT, K
    HANKE, D
    [J]. INORGANIC CHEMISTRY, 1993, 32 (14) : 3099 - 3103
  • [7] Time dependent specific heat of a magnetic quantum tunneling system
    Fernandez, JF
    Luis, F
    Bartolome, J
    [J]. PHYSICAL REVIEW LETTERS, 1998, 80 (25) : 5659 - 5662
  • [8] Heat capacity anomalies induced by magnetization quantum tunneling in a Mn12O12-acetate single crystal
    Fominaya, F
    Villain, J
    Gandit, P
    Chaussy, J
    Caneschi, A
    [J]. PHYSICAL REVIEW LETTERS, 1997, 79 (06) : 1126 - 1129
  • [9] Macroscopic measurement of resonant magnetization tunneling in high-spin molecules
    Friedman, JR
    Sarachik, MP
    Tejada, J
    Ziolo, R
    [J]. PHYSICAL REVIEW LETTERS, 1996, 76 (20) : 3830 - 3833
  • [10] SPIN TUNNELING - A PERTURBATIVE APPROACH
    GARANIN, DA
    [J]. JOURNAL OF PHYSICS A-MATHEMATICAL AND GENERAL, 1991, 24 (02): : L61 - L62