New fragmentation and rearrangement reactions of the azetidine ring promoted by AlEt2Cl

被引：10

作者：

Alcaide, B ^{[1
]}

Salgado, NR ^{[1
]}

Sierra, MA ^{[1
]}

机构：

[1] Univ Complutense Madrid, Fac Quim, Dept Quim Organ 1, E-28040 Madrid, Spain

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 5-6期

关键词：

D O I：

10.1016/S0040-4039(97)10577-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Azetidines 6 prepared by AlH2Cl reduction of easily available beta-lactams 5 react with AlEt2Cl in CH2Cl2 solution at room temperature to yield, through new fragmentation or rearrangement reactions of the azetidine ring, either, olefins 7 or bicyclic fused pyrrolidines 8,depending on the nature of the group bonded to C2 of the four membered ring. (C) 1997 Elsevier Science Ltd. All rights reserved.

引用

页码：467 / 470

页数：4

共 23 条

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