Cooperative thermal and optical switching of spin states in a new two-dimensional coordination polymer

被引：62

作者：

Niel, V

Galet, A

Gaspar, AB

Muñoz, MC

Real, JA

机构：

[1] Univ Valencia, Inst Ciencia Mol, Dept Quim Inorgan, E-46100 Burjassot, Spain

[2] Univ Politecn Valencia, Dept Fis Aplicada, E-46071 Valencia, Spain

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 11期

关键词：

D O I：

10.1039/b301806g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

{Fe(pmd)(2)[Cu(CN)(2)](2)} (pmd = pyrimidine) displays a rigid two-dimensional structure and undergoes thermal- and optical-driven spin crossover behaviour; cooperative elastic coupling between iron(II) ions in the framework induces thermal hysteresis in the HS <-> LS conversion and sigmoidal HS --> LS relaxation of the photo-induced HS state at low temperatures.

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收藏

页码：1248 / 1249

页数：2

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