Highly enantiomeric supramolecular [4+4] photocyclodimerization of 2-anthracenecarboxylate mediated by human serum albumin

被引：104

作者：

Nishijima, Masaki

Wada, Takehiko

Mori, Tadashi

Pace, Tamara C. S.

Bohne, Cornelia

Inoue, Yoshihisa

机构：

[1] Univ Victoria, Dept Chem, Victoria, BC V8W 3V6, Canada

[2] Osaka Univ, JST, ICORP, Dept Appl Chem, Suita, Osaka 5650871, Japan

[3] Osaka Univ, JST, PRESTO, Suita, Osaka 5650871, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 12期

关键词：

D O I：

10.1021/ja068475z

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Photoirradiation at lambda > 320 nm of 2-anthracenecarboxylate bound to human serum albumin in an aqueous buffer solution at 5 degrees C gave syn head-to-tail cyclodimer 2 in 82% ee and anti head-to-head cyclodimer 3 in 90% ee.

引用

页码：3478 / +

页数：3

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