Di-μ-chlorido-bis[(di-2-pyridyl disulfide-κ2N,N′)copper(I)]

被引：2

作者：

Wang, Liang-Gui ^{[1
]}

机构：

[1] Lishui Univ, Dept Chem, Lishui 323000, Zhejiang, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2007年 / 63卷

关键词：

D O I：

10.1107/S1600536807027304

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title complex, [ Cu2Cl2( C10H8N2S2) (2)], the asymmetric unit contains one and a half dinuclear copper complexes, one complex being arranged around an inversion center. In each complex, the Cu I atom is coordinated by two N atoms from one di- 2- pyridyl disulfide ligand and two bridging Cl atoms, and has a distorted tetrahedral geometry.

引用

页码：M1826 / U529

页数：12

共 10 条

[1] Reactions of trichlorovinylmercurials with potential non-chelating bidentate ligands.: Crystal structures of [(C2Cl3)2Hg (4,4′-bipyridyl)](1), [C2Cl3Hg(2-pyridyl thiolate)] (12) and polymeric HgBr2(2,2′-dipyridyl disulfide) (10) [J].

Bell, NA ;

Gelbrich, T ;

Hursthouse, MB ;

Light, ME ;

Wilson, A .

POLYHEDRON, 2000, 19 (26-27) :2539-2546

[2]

Bruker, 2002, SMART SAINT

[3]

Burnett M.N., 1996, ORTEP3

[4] Novel coordination polymers generated from angular 2,2′-dipyridyl ligands and bis(hexafluoroacetylacetonate) copper(II):: Crystal structures and magnetic properties [J].

Delgado, Salome ;

Barrilero, Aitor ;

Molina-Ontoria, Agustin ;

Medina, Manuela E. ;

Pastor, Cesar J. ;

Jimenez-Aparicio, Reyes ;

Priego, Jose L. .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2006, (14) :2746-2759

[5]

Farrugia L.J., 1997, J APPL CRYSTALLOGR, V30, P565

[6] NOVEL CRYSTAL AND MOLECULAR-STRUCTURE OF BIS[BIS(2-PYRIDYL) DISULFIDE]COPPER(I) PERCHLORATE [J].

KADOOKA, MM ;

WARNER, LG ;

SEFF, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (24) :7569-7578

[7] CRYSTAL AND MOLECULAR-STRUCTURE OF DICHLORO[BIS(2-PYRIDYL) DISULFIDE]COBALT(II) [J].

KADOOKA, MM ;

WARNER, LG ;

SEFF, K .

INORGANIC CHEMISTRY, 1976, 15 (04) :812-816

[8] Structural diversity of copper complexes with 2,2′-dipyridyldisulfide.: From dimer to infinite sheet structure both in solid state and in solution [J].

Kubo, S ;

Nishioka, T ;

Ishikawa, K ;

Kinoshita, I ;

Isobe, K .

CHEMISTRY LETTERS, 1998, (10) :1067-1068

[9]

Sheldrick G., 2017, SHELX2017, Programs for Crystal Structure Determination

[10]

Sheldrick G.M., 1996, SADABS VERSION 2008

← 1 →