Reactivity of SeOCl2 with titanium and zirconium tetrachlorides.: The unexpected formation of a μ-oxo-bridged titanium(IV) derivative

被引：5

作者：

Calderazzo, F

D'Attoma, M

Marchetti, F

Pampaloni, G

机构：

[1] Univ Pisa, Dipartimento Chim & Chim Ind, I-56126 Pisa, Italy

[2] Univ Rome La Sapienza, Dipartimento Ingn Chim Mat & Mat Prime & Met, I-00185 Rome, Italy

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2000年 / 15期

关键词：

D O I：

10.1039/b004057f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of TiCl4 with SeOCl2 affords the mu-oxo derivative [TiCl3(SeOCl2)(2)](2)(mu-O) through a deoxygenation reaction of SeOCl2 to SeCl4 whereas ZrCl4 gives 1:1 or 1:2 adducts of formula ZrCl4(SeOCl2)(n), n=1, 2.

引用

页码：2497 / 2498

页数：2

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