RPM-1: A recyclable nanoporous material suitable for ship-in-bottle synthesis and large hydrocarbon sorption

被引：474

作者：

Pan, L

Liu, HM

Lei, XG

Huang, XY

Olson, DH

Turro, NJ

Li, J ^{[1
]}

机构：

[1] Rutgers State Univ, Dept Chem & Chem Biol, Piscataway, NJ 08854 USA

[2] Univ Penn, Dept Chem Engn, Philadelphia, PA 19104 USA

[3] Columbia Univ, Dept Chem, New York, NY 10027 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 05期

关键词：

cobalt; coordination polymers; host-guest systems; photochemistry; zeolite analogues;

D O I：

10.1002/anie.200390156

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Narrow windows and large supercavities comprise the novel nanoporous coordination organometallic structure RPM-1, which has a two-fold interpenetrating 3D network containing unique open channels (see picture). RPM-1 exhibits a high sorption capacity for large hydrocarbons and superior size/shape selectivity for the photolysis of ortho-methyl dibenzyl ketone (o-MeDBK; 100% cage effect). A completely reversible structural transformation takes place between RPM-1 and a nonporous 1D compound, which allows a full recovery of the o-MeDBK derived products (100% mass balance).

引用

页码：542 / +

页数：6

共 13 条

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