Raman spectroscopy of sulfonated polystyrene resins

被引：73

作者：

Edwards, HGM ^{[1
]}

Brown, DR

Dale, JA

Plant, S

机构：

[1] Univ Bradford, Dept Chem & Forens Sci, Bradford BD7 1DP, W Yorkshire, England

[2] Univ Huddersfield, Dept Chem & Biol Sci, Huddersfield HD1 3DH, W Yorkshire, England

[3] Purolite Int Ltd, Roybinek Res & Dev Lab, Pontyclun CF72 8YL, M Glam, Wales

来源：

VIBRATIONAL SPECTROSCOPY | 2000年 / 24卷 / 02期

基金：

英国工程与自然科学研究理事会;

关键词：

sulfonate; Raman spectroscopy; polystyrene resin; sulfonic acid; industrial catalysts; quantitative;

D O I：

10.1016/S0924-2031(00)00070-9

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Raman spectroscopy has been applied to the determination of molecular structural features in sulfonated polystyrene resins. Comparison with model compounds has facilitated the identification of key molecular vibrations which are characteristic of sulfonates and their undissociated acids. Of particular importance in the current study is the ability to undertake analysis of these resins in the hydrated state, with various amounts of water being present in the resins. (C) 2000 Elsevier Science B.V. All rights reserved.

引用

页码：213 / 224

页数：12

共 19 条

[1] APPLICATIONS OF FOURIER-TRANSFORM RAMAN-SPECTROSCOPY IN THE SYNTHETIC-POLYMER FIELD
AGBENYEGA, JK
ELLIS, G
HENDRA, PJ
MADDAMS, WF
PASSINGHAM, C
WILLIS, HA
CHALMERS, J
[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1990, 46 (02): : 197 - 216
[2] ACCESSIBILITY AND CATALYTIC ACTIVITY OF SULFONIC-ACID ION-EXCHANGE RESINS IN DIFFERENT SOLVENTS
BUTTERSACK, C
[J]. REACTIVE POLYMERS, 1989, 10 (2-3): : 143 - 164
[3] Covington A. K., 1974, Journal of Solution Chemistry, V3, P603, DOI [10.1007/BF00650404, DOI 10.1007/BF00650404]
[4] SUPPORTED ACID CATALYSIS WITH ION-EXCHANGE RESINS .3. CONDENSATION BETWEEN STYRENE AND POLYMERIZED FORMALDEHYDE IN ORGANIC MEDIA
DELMAS, M
GASET, A
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1982, 17 (01): : 35 - 50
[5] THE VIBRATIONAL-SPECTRUM OF TRIFLUOROMETHANESULPHONIC ACID, CF3SO3H, AND THE DETERMINATION OF ITS DEGREES OF DISSOCIATION IN AQUEOUS-SOLUTION BY RAMAN-SPECTROSCOPY
EDWARDS, HGM
[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1989, 45 (07): : 715 - 719
[6] FOURIER-TRANSFORM VIBRATIONAL SPECTROSCOPIC STUDIES OF P-TOLUENESULFONYL HYDRAZIDE, CH3C6H4SO2NHNH2
EDWARDS, HGM
LEWIS, IR
[J]. JOURNAL OF MOLECULAR STRUCTURE, 1993, 301 : 37 - 45
[7] THE RAMAN-SPECTRUM OF ETHANESULPHONIC ACID, C2H5SO3H, AND THE ETHANESULPHONATE ION
EDWARDS, HGM
SMITH, DN
[J]. JOURNAL OF MOLECULAR STRUCTURE, 1990, 238 : 27 - 41
[8] FOURIER-TRANSFORM VIBRATIONAL SPECTROSCOPY IN THE STUDY OF POLY (ARYL ETHER SULFONE), POLY (ARYL ETHER ETHER SULFONE) AND THEIR COPOLYMERS
ELLIS, G
SANCHEZ, A
HENDRA, PJ
WILLIS, HA
CHALMERS, JM
EAVES, JG
GASKIN, WF
KRUGER, KN
[J]. JOURNAL OF MOLECULAR STRUCTURE, 1991, 247 : 385 - 395
[9] Furukawa N., 1991, CHEM SULPHONIC ACIDS, P261
[10] DEHYDRATION OF TERT-BUTYL ALCOHOL CATALYZED BY SULFONIC-ACID RESIN
GATES, BC
WISNOUSK.JS
HEATH, HW
[J]. JOURNAL OF CATALYSIS, 1972, 24 (02) : 320 - &

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