A gallium-coated gold cluster

被引：16

作者：

Anandhi, U ^{[1
]}

Sharp, PR ^{[1
]}

机构：

[1] Univ Missouri, Columbia, MO 65211 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 45期

关键词：

cluster compounds; cyclopentadienyl ligands; gallium; gold; heterometallic complexes;

D O I：

10.1002/anie.200461295

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A triangular arrangement of gold atoms is observed in the complex [Au 3(μ-Gal2)3(Cp*Ga)5], which results when a mixture of Cp*Ga and Gal3 capture the reduced Au fragments from [LAuX] (L = ligand, X = halide). The Au atoms are bonded only to Ga atoms and each other: two Au atoms are coordinated by two Cp*Ga units and one Au atom is coordinated by a single Cp*Ga unit.

引用

页码：6128 / 6131

页数：4

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