(Perylene)(3)[Bi4Br12]: A new arene pi-complex containing the [Bi4Br12] unit

被引：20

作者：

Battaglia, LP

Bellitto, C

Cramarossa, MR

Vezzosi, IM

机构：

[1] UNIV PARMA, DIPARTIMENTO CHIM GEN INORGAN ANALIT & CHIM FIS, I-43100 PARMA, ITALY

[2] CNR, IST CHIM MAT, I-00016 ROME, ITALY

[3] UNIV MODENA, DIPARTIMENTO CHIM, I-41100 MODENA, ITALY

来源：

INORGANIC CHEMISTRY | 1996年 / 35卷 / 08期

关键词：

D O I：

10.1021/ic950986r

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of perylene with anhydrous bismuth bromide leads to a new structurally characterized pi-arene complex. Arene-bismuth interactions and weak pi ...pi perylene-perylene contacts stabilize the molecular framework of tetrameric Bi4Br12 in the solid state. A one-dimensional arene-tetrameric unit-arene packing motif is observed.

引用

页码：2390 / +

共 17 条

[1]

ALMEIDA M, 1992, NATO ADV SCI I E-APP, V206, P163

[2]

[Anonymous], 1974, INT TABLES XRAY CRYS, VIV

[3] SYNTHESIS AND CHARACTERIZATION OF BISMUTH BROMIDE ARENE-PI COMPLEXES - X-RAY STRUCTURE OF BISMUTH(III) BROMIDE FLUORANTHENE-PARA-XYLENE (4/2/1) [J].