Synthesis of N,N-bis(silyloxy)enamines with a functionalized double bond

被引：30

作者：

Dilman, AD ^{[1
]}

Tishkov, AA ^{[1
]}

Lyapkalo, IM ^{[1
]}

Ioffe, SL ^{[1
]}

Kachala, VV ^{[1
]}

Strelenko, YA ^{[1
]}

Tartakovsky, VA ^{[1
]}

机构：

[1] Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 117913, Russia

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 2000年 / 17期

关键词：

D O I：

10.1039/b004268o

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The general method for the double silylation of alpha- or beta-functionalized aliphatic nitro compounds 1 leading to regio- and stereoselective formation of N,N-bis(silyloxy)enamines 3 with a functionalized double bond is elaborated. The configuration of obtained products is determined by NMR spectroscopy.

引用

页码：2926 / 2929

页数：4

共 24 条

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[4] Dilman AD, 1999, SYNTHESIS-STUTTGART, P1767
[5] Dilman AD, 1998, SYNTHESIS-STUTTGART, P181
[6] Trimethylsilyl derivatives of aliphatic nitro compounds in α,β-C,C-cross-coupling
Dilman, AD
Lyapkalo, IM
Ioffe, SL
Strelenko, YA
Tartakovsky, VA
[J]. RUSSIAN CHEMICAL BULLETIN, 2000, 49 (05) : 874 - 878
[7] DILMAN AD, UNPUB J ORG CHEM
[8] EMDE H, 1982, SYNTHESIS-STUTTGART, P1
[9] FEGER H, 1986, LIEBIGS ANN CHEM, P1456
[10] FEGER H, 1986, LIEBIGS ANN CHEM, P428

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