Industrial scale synthesis of thiophosgene and its derivatives

被引：15

作者：

Grayson, JI ^{[1
]}

机构：

[1] Fine Organ Ltd, Middlesbrough TS2 1UB, Cleveland, England

来源：

ORGANIC PROCESS RESEARCH & DEVELOPMENT | 1997年 / 1卷 / 03期

关键词：

D O I：

10.1021/op970002c

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Thiophosgene is manufactured on a mulittonne scale, using the continuous chlorination of carbon disulfide under aqueous conditions to prepare the key intermediate perchloromethyl mercaptan, The development of this process is described, and the uses of thiophosgene in the manufacture of chlorothioformates and isothiocyanates are reviewed.

引用

页码：240 / 246

页数：7

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