Design, syntheses and applications of chemical precursors to advanced ceramic materials in nanostructured forms

被引:39
作者
Sneddon, LG [1 ]
Pender, MJ [1 ]
Forsthoefel, KM [1 ]
Kusari, U [1 ]
Wei, XL [1 ]
机构
[1] Univ Penn, Dept Chem, Philadelphia, PA 19104 USA
基金
美国国家科学基金会;
关键词
polymeric organodecaboranes; nanostructures; boron carbide;
D O I
10.1016/j.jeurceramsoc.2004.07.021
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Our recent work directed at the syntheses, characterizations and applications of new organodecaborane molecular and polymeric precursors to technologically important nonoxide ceramic materials, such as boron carbide, is presented. When used in conjunction with currently available methods for nanofabrication, these new precursors enable the formation of ceramic nanostructures, including nanofibers, nanocylinders and nanoporous materials. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:91 / 97
页数:7
相关论文
共 33 条
[1]  
ASELAGE TL, 1990, PHYS CHEM CARBIDES N, V97, P12
[2]   INFRARED-SPECTRA OF BORON-CARBIDE AND ITS ISOTYPIC DERIVATIVES B12O2, B12P2, AND B12AS2 [J].
BECHER, HJ ;
THEVENOT, F .
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1974, 410 (03) :274-286
[3]  
Bill J, 1999, PRECURSOR DERIVED CE
[4]   Homogeneous metathesis polymerization by well-defined group VI and group VIII transition-metal alkylidenes: Fundamentals and applications in the preparation of advanced materials [J].
Buchmeiser, MR .
CHEMICAL REVIEWS, 2000, 100 (04) :1565-1604
[5]   Preparation of polymeric micro- and nanostructures using a template-based deposition method [J].
Cepak, VM ;
Martin, CR .
CHEMISTRY OF MATERIALS, 1999, 11 (05) :1363-1367
[6]   Chemical strategies for template syntheses of composite micro- and nanostructures [J].
Cepak, VM ;
Hulteen, JC ;
Che, GL ;
Jirage, KB ;
Lakshmi, BB ;
Fisher, ER ;
Martin, CR ;
Yoneyama, H .
CHEMISTRY OF MATERIALS, 1997, 9 (05) :1065-&
[7]   Chemical vapor deposition based synthesis of carbon nanotubes and nanofibers using a template method [J].
Che, G ;
Lakshmi, BB ;
Martin, CR ;
Fisher, ER ;
Ruoff, RS .
CHEMISTRY OF MATERIALS, 1998, 10 (01) :260-267
[8]  
EMIN D, 1986, AIP C P
[9]  
EMIN D, 1991, AIP C P
[10]   POLYMER SYNTHESIS AND ORGANOTRANSITION METAL CHEMISTRY [J].
GRUBBS, RH ;
TUMAS, W .
SCIENCE, 1989, 243 (4893) :907-915