Highly active iron imidazolylidene catalysts for atom transfer radical polymerization

被引：178

作者：

Louie, J ^{[1
]}

Grubbs, RH ^{[1
]}

机构：

[1] CALTECH, Arnold & Mabel Beckman Labs Chem Synth, Pasadena, CA 91125 USA

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 16期

关键词：

D O I：

10.1039/b003957h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Iron(ii) halides possessing highly donating imidazolylidene ligands were found to be remarkably active and efficient catalysts for the atom transfer radical polymerization of styrene and methyl methacrylate.

引用

页码：1479 / 1480

页数：2

共 27 条

[1] Living radical polymerization of methyl methacrylate with ruthenium complex: Formation of polymers with controlled molecular weights and very narrow distributions [J].

Ando, T ;

Kato, M ;

Kamigaito, M ;

Sawamoto, M .

MACROMOLECULES, 1996, 29 (03) :1070-1072

[2] Iron(II) chloride complex for living radical polymerization of methyl methacrylate [J].

Ando, T ;

Kamigaito, M ;

Sawamoto, M .

MACROMOLECULES, 1997, 30 (16) :4507-4510

[3] Reversible activation of carbon-halogen bonds by RuCl2(PPh3)3:: Halogen exchange reactions in living radical polymerization [J].

Ando, T ;

Kamigaito, M ;

Sawamoto, M .

MACROMOLECULES, 2000, 33 (08) :2819-2824

[4]

BIELAWSKI CW, 2000, IN PRESS ANGEW CHEM

[5] Controlled/'living' radical polymerization of MMA via in situ ATRP process [J].

Chen, XP ;

Qiu, KY .

CHEMICAL COMMUNICATIONS, 2000, (03) :233-234

[6] Controlled radical polymerization of methacrylic monomers in the presence of a bis(ortho-chelated) arylnickel(II) complex and different activated alkyl halides [J].

Granel, C ;

Dubois, P ;

Jerome, R ;

Teyssie, P .

MACROMOLECULES, 1996, 29 (27) :8576-8582

[7] CARBENE COMPLEXES .20. ELECTRON-RICH CARBENEIRON(0) TRIGONAL BIPYRAMIDAL CARBONYLS AND THEIR GERMANIUM(II) AND TIN(II) ANALOGS [FE(CO)3(L)(L')] (L = CN(ME)(CH2)2NME, L' = PET3, 3 COS EQUATORIAL - OR L = M(OAR)2 (EQUATORIAL-M = GE OR SN, AR = C6H2BUT2-2,6-ME-4), L' = CO) [J].

HITCHCOCK, PB ;

LAPPERT, MF ;

THOMAS, SA ;

THORNE, AJ ;

CARTY, AJ ;

TAYLOR, NJ .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 315 (01) :27-44

[8] CRYSTAL AND MOLECULAR STRUCTURE OF A TETRACARBONYL(CARBENE)IRON COMPLEX [J].

HUTTNER, G ;

GARTZKE, W .

CHEMISCHE BERICHTE-RECUEIL, 1972, 105 (08) :2714-&

[9] FeCp(CO)2I:: A phosphine-free half-metallocene-type iron(II) catalyst for living radical polymerization of styrene [J].

Kotani, Y ;

Kamigaito, M ;

Sawamoto, M .

MACROMOLECULES, 1999, 32 (20) :6877-6880

[10]

KUHN N, 1993, SYNTHESIS-STUTTGART, P561

← 1 2 3 →