Kinetics of Cl atom reactions with butadienes including isoprene

被引：33

作者：

Notario, A

Le Bras, G

Mellouki, A ^{[1
]}

机构：

[1] CNRS, Lab Combust & Syst Reactifs, F-45071 Orleans 2, France

[2] Univ Orleans, F-45071 Orleans, France

[3] Univ Castilla La Mancha, Fac Ciencias Quim, Dept Quim Fis, Ciudad Real 13071, Spain

来源：

CHEMICAL PHYSICS LETTERS | 1997年 / 281卷 / 4-6期

关键词：

D O I：

10.1016/S0009-2614(97)01303-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The laser photolysis-resonance fluorescence technique was used to determine the rate constants for the reactions of Cl atoms with 1,3-butadiene, 2-methyl-1,3 butadiene (isoprene) and 2,3-dimethyl-1,3-butadiene in the pressure range 15-60 Torr and T=(298 +/- 2) K. The obtained rate constants (in units of 10(-10) cm(3) molecule(-1) s(-1)) were as follows: 1,3-butadiene (3.48 +/- 0.10), isoprene (3.61 +/- 0.10) and 2,3-dimethyl-1,3-butadiene (3.63 +/- 0.14). These kinetic data are discussed. (C) 1997 Elsevier Science B.V.

引用

页码：421 / 425

页数：5

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