Lithium - Air Battery: Promise and Challenges

被引:2176
作者
Girishkumar, G. [1 ]
McCloskey, B. [1 ]
Luntz, A. C. [1 ]
Swanson, S. [1 ]
Wilcke, W. [1 ]
机构
[1] IBM Res Almaden, San Jose, CA 95120 USA
来源
JOURNAL OF PHYSICAL CHEMISTRY LETTERS | 2010年 / 1卷 / 14期
关键词
ORGANIC ELECTROLYTE BATTERY; POLYMER ELECTROLYTE; ION BATTERIES; LIQUID; O-2; LI; PERFORMANCE; CATALYST; ENERGY; MODEL;
D O I
10.1021/jz1005384
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The lithium-air system captured worldwide attention in 2009 as a possible battery for electric Vehicle propulsion applications. If successfully loped, 7 this battery could provide an energy source for electric vehicles rivaling that of gasoline in terms of usable energy density. However, there are numerous scientific and technical challenges that must be overcome if this alluring promise is to turn into reality. The fundamental battery chemistry during discharge is thought to be the evidence that the oxidation of lithium metal, at the anode and reduction of Oxygen from the.,. With aprotic electrolytes, as used in Li-ion batteries, there is some evidence that the process can be reversed by applying an external Potential, i.e., that such a battery can be electrically recharged. This paper summarizes the authors' view of the promise and challenges facing development of practical Li-air batteries and the current understanding, of its chemistry. However, it Must be appreciated that this' perspective represents only a snapshot in a very rapidly evolving picture.
引用
收藏
页码:2193 / 2203
页数:11
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