Structure-property-function relationships in nanoscale oxide sensors: A case study based on zinc oxide

被引:107
作者
Polarz, Sebastian [1 ]
Roy, Abhijit
Lehmann, Michael
Driess, Matthias
Kruis, Frank Einar
Hoffmann, Andreas
Zimmer, Patrick
机构
[1] Univ Konstanz, Dept Chem, D-78457 Constance, Germany
[2] Univ Duisburg Essen, Dept Elect Elect & Informat Technol, D-47057 Duisburg, Germany
[3] Dept Math & Nat Sci, D-10623 Berlin, Germany
关键词
D O I
10.1002/adfm.200700139
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Chemical sensing on oxide sensors is a complex phenomenon involving catalytic activity as well as electronic properties. Thus, the properties of oxide sensors are highly sensitive towards structural changes. Effects like surface area, grain size, and, in addition, the occurrence of defects give separate contributions to the current. Structure-property-function relationships can be elucidated using a combination of state-of-the-art analytical techniques. It is shown, that impurity atoms in the oxide lattice influence the performance of ZnO sensors more strongly than the other factors.
引用
收藏
页码:1385 / 1391
页数:7
相关论文
共 51 条
[11]   Electron microscopy image enhanced [J].
Haider, M ;
Uhlemann, S ;
Schwan, E ;
Rose, H ;
Kabius, B ;
Urban, K .
NATURE, 1998, 392 (6678) :768-769
[12]   ZUM EINFLUSS VON ADSORBIERTEM SAUERSTOFF AUF DIE ELEKTRISCHE LEITFAHIGKEIT VON ZINKOXYDKRISTALLEN [J].
HEILAND, G .
ZEITSCHRIFT FUR PHYSIK, 1954, 138 (3-4) :459-464
[13]   PIEZOELECTRIC SEMICONDUCTOR ACOUSTIC DELAY LINES [J].
Hickernell, FS .
IEEE TRANSACTIONS ON MICROWAVE THEORY AND TECHNIQUES, 1969, MT17 (11) :957-+
[14]   Zinc oxide nanoparticles with defects [J].
Ischenko, V ;
Polarz, S ;
Grote, D ;
Stavarache, V ;
Fink, K ;
Driess, M .
ADVANCED FUNCTIONAL MATERIALS, 2005, 15 (12) :1945-1954
[15]   Atomic-resolution imaging of oxygen in perovskite ceramics [J].
Jia, CL ;
Lentzen, M ;
Urban, K .
SCIENCE, 2003, 299 (5608) :870-873
[16]   Studies of the adsorption process of Ru complexes in nanoporous ZnO electrodes [J].
Keis, K ;
Lindgren, J ;
Lindquist, SE ;
Hagfeldt, A .
LANGMUIR, 2000, 16 (10) :4688-4694
[17]   Fully automated, gas sensing, and electronic parameter measurement setup for miniaturized nanoparticle gas sensors [J].
Kennedy, MK ;
Kruis, FE ;
Fissan, H ;
Mehta, BR .
REVIEW OF SCIENTIFIC INSTRUMENTS, 2003, 74 (11) :4908-4915
[18]   Tailored nanoparticle films from monosized tin oxide nanocrystals: Particle synthesis, film formation, and size-dependent gas-sensing properties [J].
Kennedy, MK ;
Kruis, FE ;
Fissan, H ;
Mehta, BR ;
Stappert, S ;
Dumpich, G .
JOURNAL OF APPLIED PHYSICS, 2003, 93 (01) :551-560
[19]   METHANOL SYNTHESIS [J].
KLIER, K .
ADVANCES IN CATALYSIS, 1982, 31 :243-313
[20]   Gas response control through structural and chemical modification of metal oxide films: state of the art and approaches [J].
Korotcenkov, G .
SENSORS AND ACTUATORS B-CHEMICAL, 2005, 107 (01) :209-232