A good bargain:: An inexpensive, air-stable ruthenium metathesis catalyst derived from α-asarone

被引：86

作者：

Grela, K ^{[1
]}

Kim, M ^{[1
]}

机构：

[1] Polish Acad Sci, Inst Organ Chem, PL-01224 Warsaw, Poland

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2003年 / 2003卷 / 06期

关键词：

homogeneous catalysis; metathesis; olefins; ruthenium;

D O I：

10.1002/ejoc.200390151

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The one-step synthesis of ruthenium carbene precatalyst 7 from inexpensive alpha-asarone [(E)-6] is described. This recyclable and easy to obtain complex can be used successfully in various types of metathesis (RCM, CM, enyne) as a cheaper and more potent substitute of the Hoveyda-type precatalyst 2b.

引用

页码：963 / 966

页数：4

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