Catalytic aerobic oxidative decarboxylation of α-hydroxy-acids.: Methyl mandelate as a benzoyl anion equivalent

被引：21

作者：

Blay, G

Fernández, B

Formentin, P

Pedro, JR ^{[1
]}

Roselló, AL

Ruiz, R

Journaux, Y

机构：

[1] Univ Valencia, Fac Quim, Dept Quim Organ, E-46100 Burjassot, Valencia, Spain

[2] Univ Paris Sud, Chim Inorgan Lab, CNRS, URA 420, F-91405 Orsay, France

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 20期

关键词：

oxidation; decarboxylation; cobalt; catalysis;

D O I：

10.1016/S0040-4039(98)00482-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The monomeric square-planar cobalt(III) complex of bis-N,N'-disubstituted oxamides catalyses the oxidative decarboxylation of alpha-hydroxy acids with molecular oxygen/pivalaldehyde with very good yields. This reaction offers an interesting alternative in the use of methyl mandelate as a convenient benzoyl anion equivalent. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：3327 / 3330

页数：4

共 11 条

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