Mechanism of growth of ZnO single crystals from hydrothermal alkali solutions

被引:89
作者
Demianets, LN [1 ]
Kostomarov, DV [1 ]
Kuz'mina, IP [1 ]
Pushko, SV [1 ]
机构
[1] Russian Acad Sci, Shubnikov Inst Crystallog, Moscow 117333, Russia
关键词
Oxide; Zinc; Growth Medium; Physical Characteristic; Zinc Oxide;
D O I
10.1134/1.1529962
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The results obtained in experiments on the growth of zinc oxide, ZnO, under hydrothermal conditions are generalized. The polar growth and nonstoichiometry of ZnO crystals are analyzed in terms of crystal chemistry with due regard for the physicochemical conditions of the growth medium. The effect of the Li+ and of di- and trivalent metal (Co2+, Fe2+, Mn2+, Fe3+, Mn3+, Sc3+, In3+,) impurities on the kinetics and some physical characteristics of ZnO crystals are studied, and the chemical reactions occur-ring on the surfaces of the (0001) and (000(1) over bar) faces are considered. (C) 2002 MAIK "Nalika/Interperiodica".
引用
收藏
页码:S86 / S98
页数:13
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