Rational synthesis of trinuclear (Wlr2) cluster from the 16-electron half-sandwich complex Cp*Ir[Se2C2(B10H10)]

被引：49

作者：

Wang, JQ ^{[1
]}

Weng, LH ^{[1
]}

Jin, GX ^{[1
]}

机构：

[1] Fudan Univ, Dept Chem, Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2005年 / 690卷 / 02期

关键词：

iridium; carborane; half-sandwich complex; chalcogenolato ligand; heterometal bonds;

D O I：

10.1016/j.jorganchem.2004.09.076

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A trinuclear cluster {Cp*Ir[Se(2)C(2)(B(10)H(10))]}(2)W(CO)(2) (3) containing Ir-W bonding was obtained from the reaction of 16-electron complex Cp*Ir[Se(2)C(2)(B(10)H(10))] with [W(CO)(3)(py)(3)] in the presence of BF(3) (.) OEt(2), and its structure has been determined by X-ray crystallography. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：249 / 252

页数：4

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