Interconnected macroporous TiO2 (anatase) as a lithium insertion electrode material

被引：49

作者：

Yamada, H ^{[1
]}

Yamato, T ^{[1
]}

Moriguchi, I ^{[1
]}

Kudo, T ^{[1
]}

机构：

[1] Nagasaki Univ, Fac Engn, Dept Appl Chem, Nagasaki 8528521, Japan

来源：

SOLID STATE IONICS | 2004年 / 175卷 / 1-4期

关键词：

inverted opal; macroporous anatase TiO2; lithium insertion;

D O I：

10.1016/j.ssi.2003.11.031

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Macroporous TiO2 (anatase) electrodes for lithium-ion batteries were synthesized by using colloidal crystals as templates, and the lithium insertion/extraction was investigated at high current densities. Polarization of lithium insertion/extraction decreased with decreasing pore size, and an electrode with 0.1-mum pore showed high capacity of 0.5 Li/TiO2 at 1.4 C and 0.13 Li/TiO2 at 28 C. The polarization of the lithium insertion/extraction was also discussed in view of electric resistance and electrolyte resistance. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：195 / 198

页数：4

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