High-temperature electronic transport properties of Fe-doped YBaCo2O5+δ

被引：24

作者：

Zhang, Xiantu

Hao, Haoshan

He, Qinglin

Hu, Xing ^{[1
]}

机构：

[1] Zhengzhou Univ, Sch Phys Engn, Zhengzhou 450052, Peoples R China

[2] Zhengzhou Univ, Phys Mat Lab, Zhengzhou 450052, Peoples R China

[3] Zhoukou Normal Univ, Dept Phys, Zhoukou 466001, Peoples R China

[4] Jiaozuo Normal Univ, Dept Phys, Jiaozuo 454001, Peoples R China

来源：

PHYSICA B-CONDENSED MATTER | 2007年 / 394卷 / 01期

关键词：

YBaCo2-xFexO5+delta; electrical resistivity; Seebeck coefficient;

D O I：

10.1016/j.physb.2007.02.027

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

The resistivity and Seebeck coefficients of YBaCo2-xFexO5+delta(0 <= x <= 0.8) were measured from room temperature (RT) to 800 degrees C. It was found that all compositions behave as p-type semiconductors in the temperature range of RT-300 degrees C. When temperature is above about 300 degrees C, both electrical resistivity and Seebeck coefficients increase with the increase of temperature due to oxygen desorption from the lattices. Fe doping tends to increase resistivity and Seebeck coefficients in all the temperature ranges measured. The calculated activation energy of conductivity is larger than that of thermopower in the semiconductor region, which means that the conduction mechanism may be determined as a small polaron hopping model. (c) 2007 Elsevier B.V. All rights reserved.

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页码：118 / 121

页数：4

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