Metal-free activation CO2 by mesoporous graphitic carbon nitride

被引：336

作者：

Goettmann, Frederic ^{[1
]}

Thomas, Arne ^{[1
]}

Antonietti, Markus ^{[1
]}

机构：

[1] Max Planck Inst Colloids & Interfaces, D-14424 Potsdam, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 15期

关键词：

carbon dioxide; heterogeneous catalysis; metal-free catalysis; Pauson-Khand reactions; phenol;

D O I：

10.1002/anie.200603478

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Doubly useful: The use of a mesoporous graphitic carbon nitride (mpg-C3N4) as a heterogeneous, metal-free catalyst enabled the direct activation of CO2 and the oxidation of benzene to phenol (see picture). The formed CO can be used in situ for subsequent reactions, as is shown for a Pauson-Khand reaction. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2717 / 2720

页数：4

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