Synthetic, structural and spectroscopic studies of (pseudo)halo(1,3-di-tert-butylimidazol-2-ylidine) gold complexes

被引：118

作者：

Baker, MV ^{[1
]}

Barnard, PJ ^{[1
]}

Brayshaw, SK ^{[1
]}

Hickey, JL ^{[1
]}

Skelton, BW ^{[1
]}

White, AH ^{[1
]}

机构：

[1] Univ Western Australia, Crawley, WA 6009, Australia

来源：

DALTON TRANSACTIONS | 2005年 / 01期

关键词：

D O I：

10.1039/b412540a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of (pseudo) halo(1,3-di-tert-butylimidazol-2-ylidine) gold complexes [(But(2)Im) AuX] (X = Cl, Br, I, CN, N-3, NCO, SCN, SeCN, ONO2, OCOCH3, CH3) have been synthesized and characterised spectroscopically and structurally. C-13 NMR chemical shifts for the carbene carbon vary widely with differing ancillary anion, correlating well with the sigma-donor ability of the latter and with the M-C-(carbene) bond distance. These results reinforce the notion that N-heterocyclic carbene ligands are primarily sigma-donor ligands with little pi-acceptor ability.

引用

页码：37 / 43

页数：7

共 35 条

[1] A STABLE CRYSTALLINE CARBENE
ARDUENGO, AJ
HARLOW, RL
KLINE, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (01) : 361 - 363
[2] PHOTOELECTRON-SPECTROSCOPY OF A CARBENE/SILYLENE/GERMYLENE SERIES
ARDUENGO, AJ
BOCK, H
CHEN, H
DENK, M
DIXON, DA
GREEN, JC
HERRMANN, WA
JONES, NL
WAGNER, M
WEST, R
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (15) : 6641 - 6649
[3] Dinuclear gold(I) complexes of bridging bidentate carbene ligands: synthesis, structure and spectroscopic characterisation
Barnard, PJ
Baker, MV
Berners-Price, SJ
Skelton, BW
White, AH
[J]. DALTON TRANSACTIONS, 2004, (07) : 1038 - 1047
[4] N-heterocyclic carbene, silylene, and germylene complexes of MCl (M = Cu, Ag, Au). A theoretical study
Boehme, C
Frenking, G
[J]. ORGANOMETALLICS, 1998, 17 (26) : 5801 - 5809
[5] REACTIONS OF C-IMIDAZOLYLLITHIUM DERIVATIVES WITH GROUP-IB COMPOUNDS - TRIS[MU-(1-ALKYLIMIDAZOLATO-N3,C2)]TRI-GOLD(I) AND TRI-SILVER(I) - CRYSTAL-STRUCTURE OF BIS(1-BENZYLIMIDAZOLIN-2-YLIDEN)GOLD(I) CHLORIDE
BONATI, F
BURINI, A
PIETRONI, BR
BOVIO, B
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 375 (01) : 147 - 160
[6] BIS(4,5-DIMETHYLIMIDAZOL-2-YLIDENE)GOLD(I) CHLORIDE HYDRATE - AN UNEXPECTED PRODUCT FROM THE REACTION OF TRIS(4,5-DIMETHYLIMIDAZOL-2-YL)PHOSPHINE AND TETRACHLOROAURIC ACID
BRITTEN, JF
LOCK, CJL
WANG, ZX
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1992, 48 : 1600 - 1603
[7] CARDIN DJ, 1971, CHEM COMMUN, P400, DOI DOI 10.1039/C29710000400
[8] CARDIN DJ, 1972, CHEM COMMUN, P927
[9] CARBENE COMPLEXES .8. CHROMIUM(0), IRON(0), RHODIUM(1), IRIDIUM(1), NICKEL(II), PALLADIUM(II), PLATINUM(II), AND GOLD(I) MONO-CARBENE AND OLIGO-CARBENE SPECIES FROM ELECTRON-RICH OLEFINS
CETINKAYA, B
DIXNEUF, P
LAPPERT, MF
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1974, (16): : 1827 - 1833
[10] CARBENE COMPLEXES .24. PREPARATION AND CHARACTERIZATION OF 2 ENETETRAMINE-DERIVED CARBENERHODIUM(I) CHLORIDE COMPLEXES RHCL(L(R))(3) AND [RHCL(COD)L(R)] (L(R)=DCN(ME)CU(CH)(4)CNME-O) AND THE PREPARATION AND X-RAY STRUCTURES OF THE ENETETRAMINE L(2)(R) AND ITS SALT [L(2)(R)][BF4](2)
CETINKAYA, E
HITCHCOCK, PB
KUCUKBAY, H
LAPPERT, MF
ALJUAID, S
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 481 (01) : 89 - 95

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