Addition of glycerol plasticizer to seaweeds derived alginates: Influence of microstructure on chemical-physical properties

被引：90

作者：

Avella, Maurizio

Di Pace, Emilia

Immirzi, Barbara

Impallomeni, Giuseppe

Malinconico, Mario

Santagata, Gabriella

机构：

[1] CNR, Inst Chem & Technol Polymers, I-80078 Pozzuoli, NA, Italy

[2] CNR, Inst Chem & Technol Polymers, I-95125 Catania, Italy

来源：

CARBOHYDRATE POLYMERS | 2007年 / 69卷 / 03期

关键词：

alginate; glycerol; microstructure; thermal and mechanical characterizations; X-RAY-DIFFRACTION; ALGINIC ACID; STRUCTURAL COMPONENTS; MECHANICAL-PROPERTIES; CRYSTALLINE-STRUCTURE; FILMS; POLYSACCHARIDES; HYDROLYSIS; SPECTROSCOPY; DIVALENT;

D O I：

10.1016/j.carbpol.2007.01.011

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A study of the interaction among sodium alginates of different molecular compositions, water and glycerol was carried out, in order to weigh up the influence of different polymeric microstructures on the chemical-physical properties of films obtained by water soluble blends of sodium alginates and increasing amounts of glycerol. Thermal, mechanical and morphological analyses performed on the films confirmed the existence of specific interactions between sodium alginates and glycerol; it was as well demonstrated that only at specific mass ratio between the single polymers and glycerol it is possible to obtain the correct plasticizing effect induced by glycerol. (C) 2007 Published by Elsevier Ltd.

引用

页码：503 / 511

页数：9

共 25 条

[1]

[Anonymous], 2003, GB/T 50081-2002 Standard for test method of mechanical properties on ordinary concreteJ

[2]

ATKINS ED, 1985, POLYSACCHARIDES TOPI

[3] STRUCTURAL COMPONENTS OF ALGINIC ACID .2. CRYSTALLINE-STRUCTURE OF POLY-ALPHA-L-GULURONIC ACID - RESULTS OF X-RAY-DIFFRACTION AND POLARIZED INFRARED STUDIES [J].