Synthesis and X-ray crystal structure of a hexanuclear silver(I) complex with non-chelating tri- and tetra-dentate bridging o-(diphenylphosphino)benzoate ligands

被引：11

作者：

Wong, WK ^{[1
]}

Zhang, LL

Wong, WT

机构：

[1] Hong Kong Baptist Univ, Dept Chem, Hong Kong, Peoples R China

[2] Univ Hong Kong, Dept Chem, Hong Kong, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 06期

关键词：

D O I：

10.1039/a708227d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Single crystal X-ray analysis of the hexanuclear silver(I) complex Ag-6[o-Ph2P(C6H4CO2)-O,P](6), synthesized by treatment of Ag(CF3SO3) with N(CH2CH2NH2)(3), 1,3-dicyclohexylcarbodiimide (DCC) and o-Ph2PC6H4(CO2H) in 1:1:3:3 molar ratio in ethanol, shows that the complex is centrosymmetric and consists of three independent silver(I) centres linking together via non-chelating tri- and tetradentate bridging o-(diphenylphosphino)benzoate groups.

引用

页码：673 / 674

页数：2

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