Ultrathin, transparent, and flexible graphene films for supercapacitor application

被引:355
作者
Yu, Aiping [1 ]
Roes, Isaac [1 ]
Davies, Aaron [1 ]
Chen, Zhongwei [1 ]
机构
[1] Univ Waterloo, Dept Chem Engn, Waterloo, ON N2L 3G1, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
capacitance; electrochemistry; graphene; scanning electron microscopy; surface morphology; thin films; transmission electron microscopy;
D O I
10.1063/1.3455879
中图分类号
O59 [应用物理学];
学科分类号
摘要
This study reports the preparation of ultrathin, transparent graphene films for use in supercapacitor applications. The surface morphology of the films was investigated by scanning electron microscopy and transmission electron microscopy, revealing a very homogeneous surface with intimate contact between graphene sheets. Electrochemical characterization demonstrated nearly ideal electrical double layer capacitive behavior. The capacitance obtained from charge-discharge analysis is 135 F/g for a film of approximately 25 nm which has a transmittance of 70% at 550 nm and a high power density of 7200 W/kg in 2 M KCl electrolyte. (C) 2010 American Institute of Physics. [doi:10.1063/1.3455879]
引用
收藏
页数:3
相关论文
共 19 条
[1]  
[Anonymous], 1999, ELECTROCHEMICAL SUPE
[2]   Electronic properties of single-walled carbon nanotube networks [J].
Bekyarova, E ;
Itkis, ME ;
Cabrera, N ;
Zhao, B ;
Yu, AP ;
Gao, JB ;
Haddon, RC .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (16) :5990-5995
[3]   Flexible and transparent supercapacitor based on In2O3 nanowire/carbon nanotube heterogeneous films [J].
Chen, Po-Chiang ;
Shen, Guozhen ;
Sukcharoenchoke, Saowalak ;
Zhou, Chongwu .
APPLIED PHYSICS LETTERS, 2009, 94 (04)
[4]   Flexible supercapacitor based on polyaniline nanowires/carbon cloth with both high gravimetric and area-normalized capacitance [J].
Horng, Ying-Ying ;
Lu, Yi-Chen ;
Hsu, Yu-Kuei ;
Chen, Chia-Chun ;
Chen, Li-Chyong ;
Chen, Kuei-Hsien .
JOURNAL OF POWER SOURCES, 2010, 195 (13) :4418-4422
[5]   PREPARATION OF GRAPHITIC OXIDE [J].
HUMMERS, WS ;
OFFEMAN, RE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (06) :1339-1339
[6]   Preparation and enhanced stability of flexible supercapacitor prepared from Nafion/polyaniline nanofiber [J].
Kim, B. C. ;
Kwon, J. S. ;
Ko, J. M. ;
Park, J. H. ;
Too, C. O. ;
Wallace, G. G. .
SYNTHETIC METALS, 2010, 160 (1-2) :94-98
[7]   Processable aqueous dispersions of graphene nanosheets [J].
Li, Dan ;
Mueller, Marc B. ;
Gilje, Scott ;
Kaner, Richard B. ;
Wallace, Gordon G. .
NATURE NANOTECHNOLOGY, 2008, 3 (02) :101-105
[8]   Carbon properties and their role in supercapacitors [J].
Pandolfo, A. G. ;
Hollenkamp, A. F. .
JOURNAL OF POWER SOURCES, 2006, 157 (01) :11-27
[9]   Asymmetric flexible supercapacitor stack [J].
Reddy, A. Leela Mohana ;
Amitha, F. Estaline ;
Jafri, Imran ;
Ramaprabhu, S. .
NANOSCALE RESEARCH LETTERS, 2008, 3 (04) :145-151
[10]   Materials for electrochemical capacitors [J].
Simon, Patrice ;
Gogotsi, Yury .
NATURE MATERIALS, 2008, 7 (11) :845-854