Unsteady 2D PEM fuel cell modeling for a stack emphasizing thermal effects

被引:39
作者
Shan, Yuyao [1 ]
Choe, Song-Yul [1 ]
Choi, Seo-Ho [1 ]
机构
[1] Auburn Univ, Dept Mech Engn, Auburn, AL 36849 USA
关键词
PEMFC; stack; dynamics; temperature distribution;
D O I
10.1016/j.jpowsour.2006.12.022
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Models currently used for analyses of thermal and water behavior of a PEM fuel cell are based 3D computational fluid dynamics (CFD). However, the analyses are limited to a single cell with static behavior. Thus, these models cannot be used for analyses of dynamic behavior of a stack that continuously varies according to operating conditions. The model proposed describes dynamic behavior of a stack with two adjoining cells and endplate assembly, and work as a current controlled voltage source that can be used for optimization of BOPs and the associated controls. Simulations have been conducted to analyze start-up behaviors and the performance of the stack. Our analyses deliver following results: (1) dynamic temperature distribution in both the through-plane direction and the along channel direction of the fuel cell stack, (2) effects influencing the source terms of current density, and (3) dynamic oxygen concentration distribution. The temperature profile and its variation propensity are comparable to the previous results [Y Shan, S.Y. Choe, J. Power Sources, 145 (1) (2005) 30-39; Y. Shan, S.Y Choe, J. Power Sources, in press]. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:196 / 209
页数:14
相关论文
共 26 条
[1]  
[Anonymous], 1980, SERIES COMPUTATIONAL, DOI [DOI 10.1201/9781482234213, 10.1201/9781482234213]
[2]   Water management in PEM fuel cells [J].
Berg, P ;
Promislow, K ;
St Pierre, J ;
Stumper, J ;
Wetton, B .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2004, 151 (03) :A341-A353
[3]  
BERG P, 2003, NANOTECHNOLOGY, V3, P493
[4]   Modelling static and dynamic behaviour of proton exchange membrane fuel cells on the basis of electro-chemical description [J].
Ceraolo, M ;
Miulli, C ;
Pozio, A .
JOURNAL OF POWER SOURCES, 2003, 113 (01) :131-144
[5]   Numerical prediction of mass-exchange between cathode and anode channels in a PEM fuel cell [J].
Dutta, S ;
Shimpalee, S ;
Van Zee, JW .
INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER, 2001, 44 (11) :2029-2042
[6]  
EATON BM, 2001, THESIS VIRGINIA POLY
[7]  
GARUA V, 1998, J AICHE, V44, P2410
[8]  
GURSKI SD, 2003, SAE 2003 WORLD C EXH
[9]   A single-phase, non-isothermal model for PEM fuel cells [J].
Ju, H ;
Meng, H ;
Wang, CY .
INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER, 2005, 48 (07) :1303-1315
[10]   ANALYSIS OF FREE-ENERGY AND ENTROPY CHANGES FOR HALF-CELL REACTIONS [J].
LAMPINEN, MJ ;
FOMINO, M .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1993, 140 (12) :3537-3546