New paradigms for synthetic pathways inspired by bioorganometallic chemistry

被引：121

作者：

Jaouen, G

Top, S

Vessières, A

Alberto, R

机构：

[1] Ecole Natl Super Chim Paris, Lab Chim Organomet, UMR 7576, F-75231 Paris 05, France

[2] Univ Zurich, Inst Anorgan Chem, CH-8057 Zurich, Switzerland

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2000年 / 600卷 / 1-2期

关键词：

radiopharmaceuticals; metal exchange reaction; decomplexation-complexation; aqueous carbonyl complexes; hormones/antihormones; rhenium; technetium; iron; titanium complexes;

D O I：

10.1016/S0022-328X(00)00036-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two series of particular examples of reactions used in bioorganometallic chemistry are described. One based on a decomplexation-complexation reaction, indicates how, starting from a cymantrenyl derivative, a range of organometallic complexes bearing various metals can be prepared. The second one refers to the easy synthesis in water of the very versatile Alberto's reagent, which leads to new organometallic radiopharmaceuticals of Tc and Re. (C) 2000 Elsevier Science S.A. All rights reserved.

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页码：23 / 36

页数：14

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