Oxidative carbonylation of methane in the presence of Rh complexes in aqueous acetic acid

被引：25

作者：

Chepaikin, EG ^{[1
]}

Boyko, GN ^{[1
]}

Bezruchenko, AP ^{[1
]}

Leshcheva, AA ^{[1
]}

Grigoryan, EH ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Struct Macrokinet, Chernogolovka 142432, Moscow Region, Russia

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1998年 / 129卷 / 01期

基金：

俄罗斯基础研究基金会;

关键词：

methane; oxidative carbonylation; rhodium complexes; acetic acid; methyl acetate;

D O I：

10.1016/S1381-1169(97)00134-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The formation of acetic acid by the oxidative carbonylation of methane in the presence of a RhCl3-DCl-KI catalytic system is strongly accelerated when an aqueous medium is substituted by an aqueous-acetic one. (C) 1998 Elsevier Science B.V.

引用

页码：15 / 18

页数：4

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