Characterization of Annona cherimola Mill. Seed Oil from Madeira Island: a Possible Biodiesel Feedstock

被引:11
作者
Branco, Pedro Costa [1 ,2 ]
Castilho, Paula C. [1 ]
Rosa, Maria Fernanda [2 ]
Ferreira, Juan [1 ]
机构
[1] Univ Madeira, Ctr Quim Madeira, P-9000390 Funchal, Portugal
[2] Inst Nacl Engn Tecnol & Inovacao, Dept Energias Renovaveis, Unidade Biomassa, P-1649038 Lisbon, Portugal
关键词
Annona seed oil; Residue valorization; Triacylglycerols; Fatty acid; Methyl ester; Biodiesel production; EDIBLE VEGETABLE-OILS; FREE FATTY-ACIDS; DIESEL-ENGINE; METHYL-ESTER; SPECTROSCOPY; TRIACYLGLYCEROLS; FUELS;
D O I
10.1007/s11746-009-1513-1
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The possibility of using Annona seed oil as an added value product, namely as a source of biodiesel, is explored. Milled Annona seeds were extracted with hexane at room temperature (72 h) and at solvent boiling point (6 h). Oil content was found to be 25 and 22.4% respectively. The oil was characterized in terms of lipid composition (HPLC-APCI-MS and (13)C NMR), resistance to oxidation and acidity index. FAME composition was determined by GC-MS and five major peaks were identified. Production of biodiesel from Annona's seed oil was achieved by base-catalyzed transesterification. Density, viscosity, refraction coefficient, acid value, cold filter plugging point, cloud point and oxidation stability were measured. The iodine value and the "apparent cetane number" were calculated. Density, viscosity, acid value, iodine value, cold filter plugging point and cloud point were within EN14214 specifications and the calculated "apparent cetane number" was also indicative of a suitable product.
引用
收藏
页码:429 / 436
页数:8
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