Polymer architectures via reversible addition fragmentation chain transfer (RAFT) polymerization

被引：45

作者：

Takolpuckdee, P ^{[1
]}

Westwood, J ^{[1
]}

Lewis, DM ^{[1
]}

Perrier, S ^{[1
]}

机构：

[1] Univ Leeds, Dept Colour & Polymer Chem, Leeds LS2 9JT, W Yorkshire, England

来源：

MACROMOLECULAR SYMPOSIA | 2004年 / 216卷

关键词：

block copolymers; cellulose graft polymer; functionalization of polymers; macromolecular architecture; reversible addition fragmentation chain transfer;

D O I：

10.1002/masy.200451204

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Various versatile chain transfer agents (CTAs) have been synthesized for reversible addition fragmentation chain transfer (RAFT) polymerzation. Such CTAs have been used to modify hydroxyl containing materials and produce well-controlled molecular architectures such as amphiphilic copolymer from poly (ethylene glycol), AB block copolymer consisting of a biodegradable segment, poly (l-lactic acid) (PLLA) and grafted copolymers of poly (styrene), poly (methyl methacrylate) and poly (methyl acrylate) from cellulose.

引用

页码：23 / 35

页数：13

共 24 条

[1] ATRP grafting from cellulose fibers to create block-copolymer grafts [J].

Carlmark, A ;

Malmström, EE .

BIOMACROMOLECULES, 2003, 4 (06) :1740-1745

[2]

Charmot D, 2000, MACROMOL SYMP, V150, P23, DOI 10.1002/1521-3900(200002)150:1<23::AID-MASY23>3.0.CO

[3]

2-E

[4] Living free-radical polymerization by reversible addition-fragmentation chain transfer: The RAFT process [J].

Chiefari, J ;

Chong, YK ;

Ercole, F ;

Krstina, J ;

Jeffery, J ;

Le, TPT ;

Mayadunne, RTA ;

Meijs, GF ;

Moad, CL ;

Moad, G ;

Rizzardo, E ;

Thang, SH .

MACROMOLECULES, 1998, 31 (16) :5559-5562

[5] A more versatile route to block copolymers and other polymers of complex architecture by living radical polymerization: The RAFT process [J].

Chong, YK ;

Le, TPT ;

Moad, G ;

Rizzardo, E ;

Thang, SH .

MACROMOLECULES, 1999, 32 (06) :2071-2074

[6]

Corpart P., 1998, Patent No. 9858974

[7]

De Brouwer H, 2000, J POLYM SCI POL CHEM, V38, P3596, DOI 10.1002/1099-0518(20001001)38:19<3596::AID-POLA150>3.0.CO

[8]

2-F

[9]

EVAN M, 2003, EUR POLYM J, V39, P633

[10] Phenolic ester-based initiators for transition metal mediated living polymerization [J].

Haddleton, DM ;

Waterson, C .

MACROMOLECULES, 1999, 32 (26) :8732-8739

← 1 2 3 →