Thiol-ene "click" reactions and recent applications in polymer and materials synthesis

被引：1351

作者：

Lowe, Andrew B. ^{[1
]}

机构：

[1] Univ New S Wales, CAMD, Sch Chem Sci & Engn, Sydney, NSW 2052, Australia

来源：

POLYMER CHEMISTRY | 2010年 / 1卷 / 01期

关键词：

FRAGMENTATION CHAIN TRANSFER; LIVING RADICAL POLYMERIZATION; WATER-SOLUBLE (CO)POLYMERS; MICHAEL ADDITION; TRANSFER RAFT; ORTHOGONAL SYNTHESIS; SURFACE MODIFICATION; BLOCK-COPOLYMERS; THIYL RADICALS; YNE REACTIONS;

D O I：

10.1039/b9py00216b

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

This review highlights examples or recent applications of both the radical-mediated and base/nucleophile-initiated thiol-ene reactions in polymer and materials synthesis. Initial discussion focuses on mechanistic aspects of these reactions and also notes some of the structural considerations, with respect to reactants, that should be considered when practising such chemistries. The review is not intended to be exhaustive but rather to serve as an illustration of the impressive versatility and clear potential of these thiol-based "click" reactions and to highlight examples demonstrating its broad utility.

引用

页码：17 / 36

页数：20

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