Spin crossover and photomagnetism in dinuclear iron(II) compounds

被引：145

作者：

Bousseksou, Azzedine

Molnar, Gabor

Real, Jose Antonio

Tanaka, Koichiro

机构：

[1] CNRS, UPR 8241, Chim Coordinat Lab, F-31077 Toulouse, France

[2] Univ Valencia, Dept Quim Inorgan, Inst Ciencia Mol, Valencia 46071, Spain

[3] Kyoto Univ, Grad Sch Sci, Dept Phys, Sakyo Ku, Kyoto 6068502, Japan

来源：

COORDINATION CHEMISTRY REVIEWS | 2007年 / 251卷 / 13-14期

关键词：

spin crossover; dinuclear complexes; LIESST effect; Ising-like model;

D O I：

10.1016/j.ccr.2007.02.023

中图分类号：

O61 [无机化学];

学科分类号：

070301 [无机化学]; 081704 [应用化学];

摘要：

In this paper, we review recent work reported in the field of molecular spin crossover phenomena in dinuclear compounds. Following a comprehensive overview on the synthesis and properties of new iron(II) dinuclear compounds presenting the spin crossover phenomenon, we focus this review on recent efforts made in studying and understanding the photo-physical properties of the {[Fe(L)(NCX)(2)](2)bpym} (L = bt or bpym, X = S or Se) family of compounds. Finally, literature on the different theoretical approaches treating the static and dynamic properties of dinuclear complexes presenting two-step thermal spin transition is briefly summarized. (C) 2007 Elsevier B.V. All rights reserved.

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页码：1822 / 1833

页数：12

相关论文

共 53 条

[1]

Strustural and magnetic resolution of a two-step full spin-crossover transition in a dinuclear iron(II) pyridyl-bridged compound [J].

Amoore, Jarrod L. M. ;

Kepert, Cameron J. ;

Cashion, John D. ;

Moubaraki, Boujemaa ;

Neville, Suzanne M. ;

Murray, Keith S. .

CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (32) :8220-8227

[2]

Dynamical Ising-like model for the two-step spin-crossover systems [J].

Boukheddaden, K ;

Linares, J ;

Codjovi, E ;

Varret, F ;

Niel, V ;

Real, JA .

JOURNAL OF APPLIED PHYSICS, 2003, 93 (10) :7103-7105

[3]

Non-linear relaxation of the photo-induced high spin state in spin-crossover solids: Effect of correlations [J].

Boukheddaden, K ;

Varret, F ;

Salunke, S ;

Linares, J ;

Codjovi, E .

PHASE TRANSITIONS, 2002, 75 (7-8) :733-741

[4]

Dynamical model for spin-crossover solids.: I.: Relaxation effects in the mean-field approach [J].

Boukheddaden, K ;

Shteto, I ;

Hôo, B ;

Varret, F .

PHYSICAL REVIEW B, 2000, 62 (22) :14796-14805

[5]

Dynamical model for spin-crossover solids.: II.: Static and dynamic effects of light in the mean-field approach [J].

Boukheddaden, K ;

Shteto, I ;

Hôo, B ;

Varret, F .

PHYSICAL REVIEW B, 2000, 62 (22) :14806-14817

[6]

BOUSSEKSOU A, 1992, J PHYS I, V2, P1381, DOI 10.1051/jp1:1992217

[7]

Ising-like model for the two step spin-crossover of binuclear molecules [J].

Bousseksou, A. ;

Varret, F. ;

Nasser, J. .

Journal De Physique, I, 1993, 3 (06)

[8]

Atypical photomagnetic properties in a series of binuclear iron(II) spin crossover complexes [J].

Chastanet, G ;

Carbonera, C ;

Mingotaud, C ;

Létard, JF .

JOURNAL OF MATERIALS CHEMISTRY, 2004, 14 (24) :3516-3523

[9]

Photo-switching spin pairs-synergy between LIESST effect and magnetic interaction in an iron(II) binuclear spin-crossover compound [J].

Chastanet, G ;

Gaspar, AB ;

Real, JA ;

Létard, JF .

CHEMICAL COMMUNICATIONS, 2001, (09) :819-820

[10]

LIGHT-INDUCED EXCITED SPIN STATE TRAPPING IN A TRANSITION-METAL COMPLEX - THE HEXA-1-PROPYLTETRAZOLE-IRON (II) TETRAFLUOROBORATE SPIN-CROSSOVER SYSTEM [J].

DECURTINS, S ;

GUTLICH, P ;

KOHLER, CP ;

SPIERING, H ;

HAUSER, A .

CHEMICAL PHYSICS LETTERS, 1984, 105 (01) :1-4

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