Gas-phase basicity of formaldehyde by the thermokinetic method

被引：8

作者：

Bouchoux, G ^{[1
]}

Leblanc, D ^{[1
]}

机构：

[1] Ecole Polytech, URA CNRS 1307, Dept Chim, Lab Mecanismes REact, F-91128 Palaiseau, France

来源：

EUROPEAN JOURNAL OF MASS SPECTROMETRY | 2000年 / 6卷 / 02期

关键词：

formaldehyde; basicity; proton affinity; thermokinetic method; FT-ICR;

D O I：

10.1255/ejms.318

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

A series of proton transfer reactions monitored in a Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometer allows the determination of the gas-phase basicity (GB) and the proton affinity (PA) of formaldehyde, The values determined by the thermokinetic method, GB(CH2O) = 681.5 +/- 0.7 kJ mol(-1) and PA(CH2O) = 711.5 +/- 2.1 kJ mol(-1) are in excellent agreement with data originating from proton transfer equilibrium constant determinations or from G2 calculations.

引用

页码：109 / 112

页数：4

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