Nucleophilic catalysis of nitrosation: relationship between nitrosating agent equilibrium constant and catalyst nucleophilicity

被引：15

作者：

da Silva, G ^{[1
]}

Kennedy, EM ^{[1
]}

Dlugogorski, BZ ^{[1
]}

机构：

[1] Univ Newcastle, Sch Engn, Proc Safety & Environm Protect Res Grp, Callaghan, NSW 2308, Australia

来源：

JOURNAL OF CHEMICAL RESEARCH-S | 2002年 / 12期

关键词：

nitrosation; nucleophilic catalysis; thermodynamic nucleophilicity;

D O I：

10.3184/030823402103171069

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Equilibrium constants for the formation of nitrosating agents from various nucleophiles and nitrous acid are predicted from Edwards' nucleophilic parameter.

引用

页码：589 / 590

页数：2

共 6 条

[1] KINETIC-STUDIES ON THE FORMATION OF N-NITROSO COMPOUNDS .9. NITROSYL ACETATE AS A NITROSATING AGENT [J].

CASADO, J ;

CASTRO, A ;

MOSQUERA, M ;

PRIETO, MFR ;

TATO, JV .

MONATSHEFTE FUR CHEMIE, 1984, 115 (6-7) :669-682

[2] KINETICS AND MECHANISM OF THE DIAZOTIZATION OF SUBSTITUTED ANILINES BY NITROSYL HALIDES - QUESTION OF DIFFUSION-CONTROLLED REACTIONS [J].

CRAMPTON, MR ;

THOMPSON, JT ;

WILLIAMS, DLH .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1979, (01) :18-22

[3]

DIX LR, 1984, J CHEM RES-S, P96

[4] MECHANISM OF NITRITE-IODIDE REACTION [J].

DOZSA, L ;

SZILASSY, I ;

BECK, MT .

INORGANICA CHIMICA ACTA, 1976, 17 (01) :147-153

[5] CORRELATION OF RELATIVE RATES AND EQUILIBRIA WITH A DOUBLE BASICITY SCALE [J].

EDWARDS, JO .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1954, 76 (06) :1540-1547

[6] NITROSATION, DIAZOTISATION, AND DEAMINATION [J].

RIDD, JH .

QUARTERLY REVIEWS, 1961, 15 (04) :418-441

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