Meso/macroporous carbon monoliths from polymeric foams

被引:44
作者
Alvarez, S
Esquena, J
Solans, C
Fuertes, AB
机构
[1] CSIC, Inst Nacl Carbon, E-33080 Oviedo, Spain
[2] CSIC, Inst Invest Quim & Ambientals Barcelona, E-08034 Barcelona, Spain
关键词
D O I
10.1002/adem.200400109
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The synthesis of meso/macroporous carbon monoliths from polymeric foams was investigated. The monoliths were obtained by templating mesostructured silica monoliths by using macroporous polystyrene foams as structure scaffolds. The TEM and SEM were used to analyze the structure of the sample monolith. The cellulose structure of the polystyrene foams was preserved in the carbon monoliths, which exhibited a fully interconnected macroporous network composed of hierarchically organised cells. The carbon skeletal was found to contain a large framework-confined porosity made up of uniform mesopores.
引用
收藏
页码:897 / 899
页数:3
相关论文
共 14 条
  • [1] Highly concentrated W/O emulsions prepared by the PIT method as templates for solid foams
    Esquena, J
    Sankar, GR
    Solans, C
    [J]. LANGMUIR, 2003, 19 (07) : 2983 - 2988
  • [2] Template synthesis of mesoporous carbons from mesostructured silica by vapor deposition polymerisation
    Fuertes, AB
    Nevskaia, DM
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2003, 13 (07) : 1843 - 1846
  • [3] Control of mesoporous structure of carbons synthesised using a mesostructured silica as template
    Fuertes, AB
    Nevskaia, DM
    [J]. MICROPOROUS AND MESOPOROUS MATERIALS, 2003, 62 (03) : 177 - 190
  • [4] Template synthesis of carbon nanotubules by vapor deposition polymerization
    Fuertes, AB
    [J]. CARBON, 2002, 40 (09) : 1600 - 1602
  • [5] Direct preparation of nanoporous carbon by nanocasting
    Han, BH
    Zhou, WZ
    Sayari, A
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (12) : 3444 - 3445
  • [6] Synthesis of new, nanoporous carbon with hexagonally ordered mesostructure
    Jun, S
    Joo, SH
    Ryoo, R
    Kruk, M
    Jaroniec, M
    Liu, Z
    Ohsuna, T
    Terasaki, O
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (43) : 10712 - 10713
  • [7] A low cost route to hexagonal mesostructured carbon molecular sieves
    Kim, SS
    Pinnavaia, TJ
    [J]. CHEMICAL COMMUNICATIONS, 2001, (23) : 2418 - 2419
  • [8] Application of large pore MCM-41 molecular sieves to improve pore size analysis using nitrogen adsorption measurements
    Kruk, M
    Jaroniec, M
    Sayari, A
    [J]. LANGMUIR, 1997, 13 (23) : 6267 - 6273
  • [9] Meso/macroporous inorganic oxide monoliths from polymer foams
    Maekawa, H
    Esquena, J
    Bishop, S
    Solans, C
    Chmelka, BF
    [J]. ADVANCED MATERIALS, 2003, 15 (7-8) : 591 - 596
  • [10] Synthesis of highly ordered carbon molecular sieves via template-mediated structural transformation
    Ryoo, R
    Joo, SH
    Jun, S
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (37): : 7743 - 7746