Jahn-Teller distortion and magnetic transitions in perovskite RMnO3 (R=Ho, Er, Tm, Yb, and Lu)

被引:127
作者
Tachibana, Makoto
Shimoyama, Tomotaka
Kawaji, Hitoshi
Atake, Tooru
Takayama-Muromachi, Eiji
机构
[1] Natl Inst Mat Sci, ICYS, Tsukuba, Ibaraki 3050044, Japan
[2] Natl Inst Mat Sci, Adv Nano Mat Lab, Tsukuba, Ibaraki 3050044, Japan
来源
PHYSICAL REVIEW B | 2007年 / 75卷 / 14期
关键词
D O I
10.1103/PhysRevB.75.144425
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The perovskite RMnO3 (R=Ho, Er, Tm, Yb, and Lu) were prepared under high pressure and studied with heat capacity and synchrotron x-ray powder diffraction measurements. The temperature interval between the antiferromagnetic transition and the first-order transition to the presumably E-type structure narrows with the decreasing ionic radius of R, and almost closes for R=Lu. Combined with the data for the larger rare earth R, the results show intricate relationship between the complex magnetic phase diagram and significant increase of Jahn-Teller distortion found for the smallest members of RMnO3.
引用
收藏
页数:5
相关论文
共 26 条
[1]   Evolution of the Jahn-Teller distortion of MnO6 octahedra in RMnO3 perovskites (R = Pr, Nd, Dy, Tb, Ho, Er, Y):: A neutron diffraction study [J].
Alonso, JA ;
Martínez-Lope, MJ ;
Casais, MT ;
Fernández-Díaz, MT .
INORGANIC CHEMISTRY, 2000, 39 (05) :917-923
[2]   Collinear to spiral spin transformation without changing the modulation wavelength upon ferroelectric transition in Tb1-xDyxMnO3 [J].
Arima, T ;
Tokunaga, A ;
Goto, T ;
Kimura, H ;
Noda, Y ;
Tokura, Y .
PHYSICAL REVIEW LETTERS, 2006, 96 (09)
[3]   Ferroelectricity and giant magnetocapacitance in perovskite rare-earth manganites [J].
Goto, T ;
Kimura, T ;
Lawes, G ;
Ramirez, AP ;
Tokura, Y .
PHYSICAL REVIEW LETTERS, 2004, 92 (25) :257201-1
[4]   Crystal and magnetic structure of the orthorhombic perovskite YbMnO3 [J].
Huang, YH ;
Fjellvåg, H ;
Karppinen, M ;
Hauback, BC ;
Yamauchi, H ;
Goodenough, JB .
CHEMISTRY OF MATERIALS, 2006, 18 (08) :2130-2134
[5]   A Rietveld-analysis program RIETAN-98 and its applications to zeolites [J].
Izumi, F ;
Ikeda, T .
EUROPEAN POWDER DIFFRACTION, PTS 1 AND 2, 2000, 321-3 :198-203
[6]   R-dependence of spin exchange interactions in RMnO3 (R = rare-earth ions) [J].
Kajimoto, R ;
Mochizuki, H ;
Yoshizawa, H ;
Shintani, H ;
Kimura, T ;
Tokura, Y .
JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 2005, 74 (09) :2430-2433
[7]   CRYSTAL DISTORTION IN MAGNETIC COMPOUNDS [J].
KANAMORI, J .
JOURNAL OF APPLIED PHYSICS, 1960, 31 (05) :S14-S23
[8]   Study of Jahn-Teller phase transitions in nonstoichiometric RMnO(3+x) orthomanganites (R=La,Nd,Sm,Eu) [J].
Kasper, NV ;
Troyanchuk, IO .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1996, 57 (11) :1601-1607
[9]   Magnetic inversion symmetry breaking and ferroelectricity in TbMnO3 -: art. no. 087206 [J].
Kenzelmann, M ;
Harris, AB ;
Jonas, S ;
Broholm, C ;
Schefer, J ;
Kim, SB ;
Zhang, CL ;
Cheong, SW ;
Vajk, OP ;
Lynn, JW .
PHYSICAL REVIEW LETTERS, 2005, 95 (08)
[10]   Heat capacity of La1-xSrxMnO3 single crystals in different magnetic states [J].
Khlopkin, MN ;
Panova, GK ;
Shikov, AA ;
Sinyavskii, VF ;
Shulyatev, DA .
PHYSICS OF THE SOLID STATE, 2000, 42 (01) :114-119