Liquidus temperatures and phase compositions in the system Qz-Ab-Or at 5 kbar and very low water activities

Liquidus phase relations have been experimentally determined in the systems Qz-Ab-Or-(H2O), Qz-Ab-(H2O) and Qz-Or-(H2O) at H2O-undersaturated conditions (a(H2O) = 0.07) and P = 5 kbar. Starting materials were homogeneous synthetic glasses containing 1 wt% H2O. The liquidus temperatures were bracketed by crystallization and dissolution experiments. The results of kinetic studies showed that crushed glasses are the best starting materials to overcome undercooling and to minimize the temperature difference between the lowest temperature of complete dissolution (melting) and the highest temperature at which crystallization can be observed. At P = 5 kbar and a(H2O) = 0.07, the Qz-Ab eutectic composition is Qz(32)Ab(68) at 1095 degrees C (+/- 10 degrees C) and the Qz-Or eutectic is Qz(38)Or(62) at 1030 degrees C (+/- 10 degrees C). The minimum temperature of the ternary system Qz-Ab-Or is 990 degrees C (+/- 10 degrees C) and the minimum composition is Qz(32)Ab(35)Or(33) The Oz content of the minimum composition in the system Qz-Ab-Or-H2O remains constant with changing a(H2O) The normative Or content, however, increases by approximately 10 wt% with decreasing a(H2O) from 1 to 0.07. Such an increase has already been observed in the system Qz-Ab-Or-H2O-CO2 at high a(H2O) and it is concluded that the use of CO2 to reduce water activities does not influence the composition of the minima in quartz-feldspar systems. The determined liquidus temperature in melts with 1 wt% H2O is very similar to that obtained in previous nominally "dry" experiments. This discrepancy is interpreted to be due to problems in obtaining absolutely dry conditions. Thus, the hitherto published solidus and liquidus temperatures for "dry" conditions are probably underestimated.