A polymeric nickel(II) thiocyanate complex of N-(2-aminoethyl)-N-methyl-1,2-ethanediamine

被引：7

作者：

Nayak, NP ^{[1
]}

Mukherjee, AK

Mondal, A

Chaudhuri, NR

机构：

[1] Jadavpur Univ, Dept Phys, Calcutta 700032, W Bengal, India

[2] Indian Assoc Cultivat Sci, Dept Inorgan Chem, Calcutta 700032, W Bengal, India

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 1998年 / 54卷

关键词：

D O I：

10.1107/S0108270197013280

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structure of [Ni(medien)(NCS)(mu-SCN)](n) [medien is N-(2-aminoethyl)-N-methyl-1,2-ethanediamine, C5H15N3] is a polymeric chain with each pair of neighbouring nickel(II) ions linked by one SCN-bridging ligand. The coordination polyhedron about the Ni-II atom is a distorted octahedron consisting of three N atoms of the medien ligand coordinating facially, one N atom of the non-bridging thiocyanate ligand, and one N and one S atom of two bridging thiocyanate ligands. The five-membered chelate rings display envelope geometry.

引用

页码：208 / 210

页数：3

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