Synthesis of a Re-Pt2 complex with bridging sulfido ligands

被引：5

作者：

Pawlicki, SH ^{[1
]}

Noll, BC ^{[1
]}

Dubois, RM ^{[1
]}

机构：

[1] Univ Colorado, Dept Chem & Biochem, Boulder, CO 80309 USA

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2003年 / 56卷 / 01期

关键词：

trimetallic; rhenium; platinum; mu-sulfido; oxo;

D O I：

10.1080/0095897021000039089

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of Cp'ReCl2S3 (where Cp'= C5EtMe4) with Pt(PPh3)(3) in toluene in air results in the formation of the heteronuclear product [Cp'ReO(mu(3)-S)(2)Pt-2(PPh3)(3)Cl]ReO4, 1. The product has been characterized by spectroscopic methods, cyclic voltammetry and by an X-ray diffraction study. The cation contains an unusual triangular array of one rhenium and two platinum ions with one Pt-Re bond. Under the same reaction conditions, the reaction of the known platinum dimer (PPh3)(4)Pt-2(mu-S)(2) with Cp'ReOCl2 was unsuccessful as a route to the cation of 1.

引用

页码：41 / 47

页数：7

共 42 条

[1] RHENIUM PLATINUM MIXED-METAL CLUSTERS - SYNTHESIS AND SOLID-STATE STRUCTURAL CHARACTERIZATION OF [RE2PT(MU-H)2(CO)8(COD)] AND OF [RE3PT(MU-H)3(CO)14]
ANTOGNAZZA, P
BERINGHELLI, T
DALFONSO, G
MINOJA, A
CIANI, G
MORET, M
SIRONI, A
[J]. ORGANOMETALLICS, 1992, 11 (05) : 1777 - 1784
[2] HETEROBIMETALLIC ALKYL POLYHYDRIDE COMPLEXES OF RHENIUM AND PLATINUM
BATSANOV, AD
HOWARD, JAK
LOVE, JB
SPENCER, JL
[J]. ORGANOMETALLICS, 1995, 14 (12) : 5657 - 5664
[3] Rhenium-platinum mixed-metal spiked-triangle clusters. Synthesis and X-ray characterization of the cluster anions [Re2Pt(mu-H)(2)(CO)(9){Re(CO)(5)}](-) and [Re2Pt(mu-H)(2)(CO)(9){HRe2(CO)(9)}](-)
Bergamo, M
Beringhelli, T
DAlfonso, G
Ciani, G
Moret, M
Sironi, A
[J]. ORGANOMETALLICS, 1996, 15 (06) : 1637 - 1644
[4] MUTUAL EXCHANGE AND ISOMERIZATION PROCESSES IN THE 3 ISOMERS OF THE MIXED-METAL TRIANGULAR CLUSTER COMPLEX [RE2PT(MU-H)2(CO)8(PPH3)2]
BERINGHELLI, T
DALFONSO, G
MINOJA, AP
[J]. ORGANOMETALLICS, 1991, 10 (02) : 394 - 400
[5] MIXED-METAL RHENIUM-PLATINUM CLUSTER COMPOUNDS - SYNTHESIS AND CHARACTERIZATION OF 3 ISOMERS OF THE TRIANGULAR CLUSTER COMPLEX [RE2PT(MU-H)2(CO)8(PPH3)2]
BERINGHELLI, T
CERIOTTI, A
DALFONSO, G
DELLAPERGOLA, R
CIANI, G
MORET, M
SIRONI, A
[J]. ORGANOMETALLICS, 1990, 9 (04) : 1053 - 1059
[6] THE ROLE OF DEPOSITED POISONS AND CRYSTALLITE SURFACE-STRUCTURE IN THE ACTIVITY AND SELECTIVITY OF REFORMING CATALYSTS
BISWAS, J
BICKLE, GM
GRAY, PG
DO, DD
BARBIER, J
[J]. CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 1988, 30 (02): : 161 - 247
[7] Synthesis and Characterization of {Re(CO)3}4-n{PtMe3}n(OH)4, (n=1-3).: A Set of heterobimetallic hydroxy cubane Complexes
Brand, U
Wright, CA
Shapley, JR
[J]. INORGANIC CHEMISTRY, 1999, 38 (25) : 5910 - +
[8] ATTEMPTED GENERATION OF CP(CO)2RE(MU-H)PT(PPH3)2[C(CH3)=CHCH3] FROM REACTION OF CP(CO)2REH- WITH (PPH3)3PT[(E)-C(CH3)=CHCH3]+ PRODUCES CP(CO)2RE(CIS-CH3CH=CHCH3)
CASEY, CP
WANG, Y
[J]. ORGANOMETALLICS, 1992, 11 (01) : 13 - 15
[9] SYNTHESIS OF RHENIUM ALKENE COMPLEXES FROM THE REACTION OF THE HETEROBIMETALLIC DIHYDRIDE C5H5(CO)2HRE-PTH(PPH3)2 WITH ALKYNES
CASEY, CP
RUTTER, EW
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (24) : 8917 - 8919
[10] SYNTHESIS OF A HETEROBIMETALLIC DIHYDRIDE BY THE ADDITION OF A RHENIUM DIHYDRIDE TO A PLATINUM(0) COMPLEX
CASEY, CP
RUTTER, EW
HALLER, KJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (22) : 6886 - 6887

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