First tether-directed regioselective bis-functionalisation of C70:: effects of cation complexation on the redox properties of diastereoisomeric fullerene crown ether conjugates

被引：35

作者：

van Eis, MJ

Alvarado, RJ

Echegoyen, L ^{[1
]}

Seiler, P

Diederich, F

机构：

[1] Univ Miami, Dept Chem, Coral Gables, FL 33124 USA

[2] ETH Zentrum, Organ Chem Lab, CH-8092 Zurich, Switzerland

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 19期

关键词：

D O I：

10.1039/b006066f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The covalently templated bis-functionalisation of C-70, employing a dibenzo-18-crown-6 tether, proceeds with complete regiospecificity and provides a bis-addition pattern which is disfavoured in sequential transformations.

引用

页码：1859 / 1860

页数：2

共 27 条

[1] SIR92 - a program for automatic solution of crystal structures by direct methods [J].

ALTOMARE, A ;

CASCARANO, G ;

GIACOVAZZO, G ;

GUAGLIARDI, A ;

BURLA, MC ;

POLIDORI, G ;

CAMALLI, M .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1994, 27 :435-435

[2] (ETA-2-C70)IR(CO)CL(PPH3)2 - THE SYNTHESIS AND STRUCTURE OF AN ORGANOMETALLIC DERIVATIVE OF A HIGHER FULLERENE [J].

BALCH, AL ;

CATALANO, VJ ;

LEE, JW ;

OLMSTEAD, MM ;

PARKIN, SR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (23) :8953-8955

[3] STRUCTURE OF A PRODUCT OF DOUBLE ADDITION TO C-70 - [C70(IR(CO)CL(PPHME2)2)2].3C6H6 [J].

BALCH, AL ;

LEE, JW ;

OLMSTEAD, MM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1992, 31 (10) :1356-1358

[4] Patterns of multiple additions to fullerene C-70: Isolation and structural characterization of [C-70{Pf(PPh(3))(2)}(4)] [J].

Balch, AL ;

Hao, LJ ;

Olmstead, MM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (02) :188-190

[5]

BINGEL C, 1995, LIEBIGS ANN, P1551

[6]

Bourgeois JP, 1998, ANGEW CHEM INT EDIT, V37, P2118, DOI 10.1002/(SICI)1521-3773(19980817)37:15<2118::AID-ANIE2118>3.0.CO

[7]

2-9

[8]

Bourgeois JP, 1999, HELV CHIM ACTA, V82, P1572, DOI 10.1002/(SICI)1522-2675(19991006)82:10<1572::AID-HLCA1572>3.0.CO

[9]

2-B

[10] CRYSTAL STRUCTURES OF COMPLEXES BETWEEN ALKALI-METAL SALTS AND CYCLIC POLYETHERS .1. COMPLEX FORMED BETWEEN RUBIDIUM SODIUM ISOTHIOCYANATE AND 2,3,11,12-DIBENZO-1,4,7,10,13,16- HEXAOXOCYCLO-OCTADECA-2,11-DIENE (DIBENZO-18-CROWN-6) [J].

BRIGHT, D ;

TRUTER, MR .

JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC, 1970, (08) :1544-&

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