On the reductive amination of aldehydes and ketones catalyzed by homogeneous Rh(I) complexes

被引：101

作者：

Tararov, VI

Kadyrov, R

Riermeier, TH

Börner, A

机构：

[1] Univ Rostock EV, Inst Organ Katalyseforsch, D-18055 Rostock, Germany

[2] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 117813, Russia

[3] Aventis Res & Technol GmbH, D-65926 Frankfurt, Germany

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 19期

关键词：

D O I：

10.1039/b005777k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The homogeneously catalyzed reductive amination of aldehydes and ketones under smooth conditions is reported, showing for the first time, that Rh(i) catalysts based on chelating diphosphines and diphosphinites can be advantageously employed for this reaction, even for the production of chiral amino acid derivatives.

引用

页码：1867 / 1868

页数：2

共 18 条

[1] Reductive amination of aldehydes and ketones with sodium triacetoxyborohydride. Studies on direct and indirect reductive amination procedures [J].

AbdelMagid, AF ;

Carson, KG ;

Harris, BD ;

Maryanoff, CA ;

Shah, RD .

JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (11) :3849-3862

[2]

BELLER M, 1998, TRANSITION METALS OR, V1

[3]

BELLER M, 1998, TRANSITION METALS OR, V2

[4]

BERENS U, 1995, J ORG CHEM, V60, P8294

[5]

Blaser HU, 1999, SYNLETT, P867

[6]

Cornils B., 1996, APPL HOMOGENEOUS CAT, V2

[7]

Cornils B., 1996, APPL HOMOGENEOUS CAT, V1

[8] Reductive N-alkylation of amides, carbamates and ureas [J].

Dubé, D ;

Scholte, AA .

TETRAHEDRON LETTERS, 1999, 40 (12) :2295-2298

[9] Tandem reaction sequences under hydroformylation conditions:: New synthetic applications of transition metal catalysis [J].

Eilbracht, P ;

Bärfacker, L ;

Buss, C ;

Hollmann, C ;

Kitsos-Rzychon, BE ;

Kranemann, CL ;

Rische, T ;

Roggenbuck, R ;

Schmidt, A .

CHEMICAL REVIEWS, 1999, 99 (11) :3329-3365

[10]

Emerson W. S., 1948, ORG REACTIONS, V4, P174

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