Phase diagrams in the Ni-Mn-Ga system under compression

被引:70
作者
Chernenko, VA [1 ]
Kokorin, VV [1 ]
Babii, OM [1 ]
Zasimchuk, IK [1 ]
机构
[1] Inst Magnetism, UA-252680 Kiev, Ukraine
关键词
intermetallics; miscellaneous; shape-memory effects; phase diagram; thermodynamic and thermochemical properties;
D O I
10.1016/S0966-9795(97)00050-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Some thermodynamic aspects of transformation behavior of two shape-memory and superelastic L2(1) ordered single-crystalline Ni-Mn-Ga alloys exhibiting martensitic transformation in the stress-free state at M-s = 287 K < T-c (alloy 1) and M-s = 428 K > T-c (alloy 2), where T-c is Curie temperature, was studied in compression (hydrostatic and/or uniaxial along [110] axis) tests. The uniaxial compression experimental results for alloy 1 which exhibits multiphase stress-induced transformation behavior as well as literature data were summarized in non-equilibrium sigma-T phase diagrams. The phenomenological treatment of the equilibrium high hydrostatic pressure versus transformation temperature data for alloys 1 and 2, i.e. p-T diagrams, was found to be useful in the framework of both the Clausius-Clapeyron relationship and Landau-type theory. Published by Elsevier Science Limited. All rights reserved.
引用
收藏
页码:29 / 34
页数:6
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