Photodimerisation of acenaphthylene in a clay microenvironment

被引：7

作者：

Madhavan, D ^{[1
]}

Pitchumani, K ^{[1
]}

机构：

[1] Madurai Kamaraj Univ, Sch Chem, Madurai 625021, Tamil Nadu, India

来源：

PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES | 2003年 / 2卷 / 02期

关键词：

D O I：

10.1039/b209795h

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The photochemical dimerisation of acenaphthylene in the presence of various cation-exchanged bentonite clays has been studied. While the cis-dimer is the predominant product when smaller cations are present in the clay interlayer, the presence of heavier atoms in the clay favors the trans-dimer. Synthetic anionic hydrotalcite clays are also found to be efficient for the efficient dimerisation of acenaphthylene.

引用

页码：95 / 97

页数：3

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