Nanofibers from self-assembly of an aromatic facial amphiphile with oligo(ethylene oxide) dendrons

被引:27
作者
Hong, Dong-Je
Lee, Eunji
Lee, Myongsoo [1 ]
机构
[1] Yonsei Univ, Ctr Supramol Nanoassembly, Seoul 120749, South Korea
[2] Yonsei Univ, Dept Chem, Seoul 120749, South Korea
关键词
BLOCK-COPOLYMER; ORGANIZATION; MATTER;
D O I
10.1039/b617404c
中图分类号
O6 [化学];
学科分类号
070301 [无机化学];
摘要
Novel block facial amphiphiles consisting of a laterally extended aromatic segment and oligo( ethylene oxide) dendrons as a flexible segment were synthesized in a stepwise fashion and their aggregation behavior was investigated in aqueous solution; self-assembly into elongated nanofibers with a uniform diameter of 7 +/- 0.5 nm and lengths up to several hundred nanometers was observed.
引用
收藏
页码:1801 / 1803
页数:3
相关论文
共 27 条
[1]
Helical nanofibers from aqueous self-assembly of an oligo(p-phenylene)-based molecular dumbbell [J].
Bae, J ;
Choi, JH ;
Yoo, YS ;
Oh, NK ;
Kim, BS ;
Lee, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (27) :9668-9669
[2]
Self-assembled smectic phases in rod-coil block copolymers [J].
Chen, JT ;
Thomas, EL ;
Ober, CK ;
Mao, GP .
SCIENCE, 1996, 273 (5273) :343-346
[3]
Polymer vesicles [J].
Discher, DE ;
Eisenberg, A .
SCIENCE, 2002, 297 (5583) :967-973
[4]
Mastering molecular matter. Supramolecular architectures by hierarchical self-assembly [J].
Elemans, JAAW ;
Rowan, AE ;
Nolte, RJM .
JOURNAL OF MATERIALS CHEMISTRY, 2003, 13 (11) :2661-2670
[5]
Porphyrin clips derived from diphenylglycoluril. Synthesis, conformational analysis, and binding properties [J].
Elemans, JAAW ;
Claase, MB ;
Aarts, PPM ;
Rowan, AE ;
Schenning, APHJ ;
Nolte, RJM .
JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (19) :7009-7016
[6]
Förster S, 2002, ANGEW CHEM INT EDIT, V41, P689
[7]
Cylindrical micelles from the aqueous self-assembly of an amphiphilic poly(ethylene oxide)-b-poly(ferrocenylsilane) (PEO-b-PFS) block copolymer with a metallo-supramolecular linker at the block junction [J].
Gohy, JF ;
Lohmeijer, BGG ;
Alexeev, A ;
Wang, XS ;
Manners, I ;
Winnik, MA ;
Schubert, US .
CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (17) :4315-4323
[8]
Self-assembled hexa-peri-hexabenzocoronene graphitic nanotube [J].
Hill, JP ;
Jin, WS ;
Kosaka, A ;
Fukushima, T ;
Ichihara, H ;
Shimomura, T ;
Ito, K ;
Hashizume, T ;
Ishii, N ;
Aida, T .
SCIENCE, 2004, 304 (5676) :1481-1483
[9]
About supramolecular assemblies of π-conjugated systems [J].
Hoeben, FJM ;
Jonkheijm, P ;
Meijer, EW ;
Schenning, APHJ .
CHEMICAL REVIEWS, 2005, 105 (04) :1491-1546
[10]
On the origins of morphological complexity in block copolymer surfactants [J].
Jain, S ;
Bates, FS .
SCIENCE, 2003, 300 (5618) :460-464