Different Structural Networks Determined by Variation of the Ligand Skeleton in Copper(II) Diphosphinate Coordination Polymers

被引：37

作者：

Costantino, Ferdinando ^{[2
,3
]}

Ienco, Andrea ^{[1
]}

Midollini, Stefano ^{[1
]}

机构：

[1] CNR, Ist Chim Composti Organo Metall, I-50019 Florence, Italy

[2] Univ Perugia, Dipartimento Chim, I-06123 Perugia, Italy

[3] Univ Perugia, CEMIN, I-06123 Perugia, Italy

来源：

CRYSTAL GROWTH & DESIGN | 2010年 / 10卷 / 01期

关键词：

INORGANIC-ORGANIC HYBRIDS; P; P'-DIPHENYLMETHYLENEDIPHOSPHINIC ACID; COMPLEXES; ISOMERISM; PCP(2-); METALS; DESIGN;

D O I：

10.1021/cg900748r

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new polymeric copper(II)-organic framework. [[Cu(4,4'-bipy)(p(xyl)p)(H2O)(2)]center dot 2(H2O)](n) (1; p(xyl)p = P,P'-diphenyl-p-xylenediphosphinate, 4,4'-bipy = 4,4'-bipyridine), has been synthesized. Single-crystal X-ray diffraction revealed that the structure of I consists of 2D grids connected by solvent water molecules, The temperature-dependent X-ray powder diffraction analysis of I has shown file formation of a dehydrated phase well modeled by a 3D structure with it binodal 4,6 connected topology.

引用

页码：7 / 10

页数：4

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