Novel μ-methyl complexes of vanadium and their relevance to bimolecular deactivation of homogeneous imidovanadium polymerisation catalysts

被引：68

作者：

Chan, MCW

Cole, JM

Gibson, VC ^{[1
]}

Howard, JAK

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England

[2] Univ Durham, Dept Chem, Durham DH1 3LE, England

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 24期

关键词：

D O I：

10.1039/a705256a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Attempted dimethylation of [CpV(NC6H3Pr2i-2,6)]Cl-2 using Grignard reagents affords novel mu-methyl complexes arising by reductive dimerisation; the structure of one of these products, [CpV(NC6H3Pr2i-2,6)(mu-Me)(2)](2)(mu-Mg) 2, reveals V-(mu-Me)-Mg, V-Mg, N-Mg and C-H ... Mg interactions.

引用

页码：2345 / 2346

页数：2

共 42 条

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